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- W2109156664 abstract "Werner complexes go organic! When orange aqueous solutions of [Co(1,2-diamine)3]X3 (X=I, Cl) are treated with solutions of NaBArf in CH2Cl2 (1:3 mol ratio), the aqueous phases decolorize (see scheme) and [Co(1,2-diamine)3](BArf)3⋅nH2O can be isolated from the CH2Cl2 phases (78–89 %). The ethylenediamine complex can catalyze enantioselective Michael additions, presumably by an outer-coordination-sphere mechanism involving hydrogen bonding. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2111/2008/z800226_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
- W2109156664 created "2016-06-24" @default.
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- W2109156664 date "2008-06-11" @default.
- W2109156664 modified "2023-10-17" @default.
- W2109156664 title "Phase Transfer of Enantiopure Werner Cations into Organic Solvents: An Overlooked Family of Chiral Hydrogen Bond Donors for Enantioselective Catalysis" @default.
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- W2109156664 doi "https://doi.org/10.1002/chem.200800226" @default.
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