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• W2109200392 abstract "A simple “pseudo-atomic” model is presented to explain the ligand field splitting of the core Zn 3d and Cd 44 orbitals in the photoelectron spectra of Me2Zn and Me2Cd respectively. We consider the electrostatic interaction between the valence pz electrons and the core d vacancy. Using the excess pz population as an adjustable factor, we are able to obtain good agreement with the observed line positions. The pz excess population determined above has also been employed to calculate the splittings of the Cd 4p, 3d and 3p vacancy levels and the 111Cd nuclear electric field gradient in Me2Cd." @default.
• W2109200392 created "2016-06-24" @default.
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• W2109200392 date "1978-03-01" @default.
• W2109200392 modified "2023-10-18" @default.
• W2109200392 title "Core level ligand field splitting in photoelectron spectra: a theoretical model for covalent molecules" @default.
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• W2109200392 doi "https://doi.org/10.1016/0009-2614(78)80089-x" @default.
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