Matches in SemOpenAlex for { <https://semopenalex.org/work/W2109316425> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2109316425 endingPage "79" @default.
- W2109316425 startingPage "72" @default.
- W2109316425 abstract "Selective hydrogenation of benzonitrile was studied with Ni/Al2O3 in compressed CO2, hexane–CO2, ethanol–CO2 and H2O–CO2 systems. The phase behavior and the effect of CO2 on the conversion of benzonitrile and the yield of benzylamine were discussed. The reaction rate was retarded in solventless, hexane and ethanol, but accelerated in water in the presence of compressed CO2. The decrease in reaction rate was mainly ascribed to the formation of carbamate from benzylamine and the intermediate 1-aminodibenzylamine reacting with CO2, and it precipitated out to coat on the surface of catalyst in solventless and hexane, and the dilution effect of compressed CO2 in ethanol. But the yield of benzylamine was increased in solventless, hexane and ethanol due to the following nucleophilic addition of benzylamine and benzylimine to N-benzylidenebenzylamine was inhibited. Although, the reaction rate increased in water for the enhanced solubility of H2 and benzonitrile in H2O and decreased mass-transfer resistance in the presence of compressed CO2, the yield of benzylamine decreased because of the acidic nature of H2O–CO2 favorites the elimination of NH3 and the formation of NH4HCO3. Accordingly, the possible reaction pathway of benzonitrile hydrogenation was proposed for all the studied systems." @default.
- W2109316425 created "2016-06-24" @default.
- W2109316425 creator A5020582929 @default.
- W2109316425 creator A5035588479 @default.
- W2109316425 creator A5050627200 @default.
- W2109316425 creator A5060261172 @default.
- W2109316425 creator A5085424514 @default.
- W2109316425 creator A5091831787 @default.
- W2109316425 date "2013-11-01" @default.
- W2109316425 modified "2023-09-30" @default.
- W2109316425 title "Selective hydrogenation of benzonitrile in multiphase reaction systems including compressed carbon dioxide over Ni/Al2O3 catalyst" @default.
- W2109316425 cites W1975425582 @default.
- W2109316425 cites W1985713568 @default.
- W2109316425 cites W1989110589 @default.
- W2109316425 cites W1998745454 @default.
- W2109316425 cites W1999755922 @default.
- W2109316425 cites W2004610182 @default.
- W2109316425 cites W2011045797 @default.
- W2109316425 cites W2011940924 @default.
- W2109316425 cites W2014663366 @default.
- W2109316425 cites W2016481372 @default.
- W2109316425 cites W2016682012 @default.
- W2109316425 cites W2017178788 @default.
- W2109316425 cites W2025340185 @default.
- W2109316425 cites W2048989043 @default.
- W2109316425 cites W2053923926 @default.
- W2109316425 cites W2056537679 @default.
- W2109316425 cites W2061712538 @default.
- W2109316425 cites W2061788527 @default.
- W2109316425 cites W2064209624 @default.
- W2109316425 cites W2072696775 @default.
- W2109316425 cites W2080814454 @default.
- W2109316425 cites W2093965297 @default.
- W2109316425 cites W2097833736 @default.
- W2109316425 cites W2135051669 @default.
- W2109316425 cites W2178638536 @default.
- W2109316425 doi "https://doi.org/10.1016/j.molcata.2013.07.017" @default.
- W2109316425 hasPublicationYear "2013" @default.
- W2109316425 type Work @default.
- W2109316425 sameAs 2109316425 @default.
- W2109316425 citedByCount "27" @default.
- W2109316425 countsByYear W21093164252015 @default.
- W2109316425 countsByYear W21093164252016 @default.
- W2109316425 countsByYear W21093164252017 @default.
- W2109316425 countsByYear W21093164252018 @default.
- W2109316425 countsByYear W21093164252019 @default.
- W2109316425 countsByYear W21093164252020 @default.
- W2109316425 countsByYear W21093164252021 @default.
- W2109316425 countsByYear W21093164252022 @default.
- W2109316425 countsByYear W21093164252023 @default.
- W2109316425 crossrefType "journal-article" @default.
- W2109316425 hasAuthorship W2109316425A5020582929 @default.
- W2109316425 hasAuthorship W2109316425A5035588479 @default.
- W2109316425 hasAuthorship W2109316425A5050627200 @default.
- W2109316425 hasAuthorship W2109316425A5060261172 @default.
- W2109316425 hasAuthorship W2109316425A5085424514 @default.
- W2109316425 hasAuthorship W2109316425A5091831787 @default.
- W2109316425 hasConcept C134121241 @default.
- W2109316425 hasConcept C155574463 @default.
- W2109316425 hasConcept C161790260 @default.
- W2109316425 hasConcept C178790620 @default.
- W2109316425 hasConcept C185592680 @default.
- W2109316425 hasConcept C191897082 @default.
- W2109316425 hasConcept C192562407 @default.
- W2109316425 hasConcept C2776276205 @default.
- W2109316425 hasConcept C2777077568 @default.
- W2109316425 hasConcept C2779953769 @default.
- W2109316425 hasConcept C2780161600 @default.
- W2109316425 hasConceptScore W2109316425C134121241 @default.
- W2109316425 hasConceptScore W2109316425C155574463 @default.
- W2109316425 hasConceptScore W2109316425C161790260 @default.
- W2109316425 hasConceptScore W2109316425C178790620 @default.
- W2109316425 hasConceptScore W2109316425C185592680 @default.
- W2109316425 hasConceptScore W2109316425C191897082 @default.
- W2109316425 hasConceptScore W2109316425C192562407 @default.
- W2109316425 hasConceptScore W2109316425C2776276205 @default.
- W2109316425 hasConceptScore W2109316425C2777077568 @default.
- W2109316425 hasConceptScore W2109316425C2779953769 @default.
- W2109316425 hasConceptScore W2109316425C2780161600 @default.
- W2109316425 hasLocation W21093164251 @default.
- W2109316425 hasOpenAccess W2109316425 @default.
- W2109316425 hasPrimaryLocation W21093164251 @default.
- W2109316425 hasRelatedWork W1977833992 @default.
- W2109316425 hasRelatedWork W2027042067 @default.
- W2109316425 hasRelatedWork W2047888616 @default.
- W2109316425 hasRelatedWork W2317066039 @default.
- W2109316425 hasRelatedWork W2371146524 @default.
- W2109316425 hasRelatedWork W2382180139 @default.
- W2109316425 hasRelatedWork W2951222599 @default.
- W2109316425 hasRelatedWork W2952261957 @default.
- W2109316425 hasRelatedWork W2952496829 @default.
- W2109316425 hasRelatedWork W3138908873 @default.
- W2109316425 hasVolume "379" @default.
- W2109316425 isParatext "false" @default.
- W2109316425 isRetracted "false" @default.
- W2109316425 magId "2109316425" @default.
- W2109316425 workType "article" @default.