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- W2109322021 abstract "Molecules of copper phthalocyanine substituted with four 18-crown-6 moieties, were aggregated with the help of K+, Rb+, and Cs+ picrates. Possible structures were proposed based on computer analysis of X-ray powder diffraction patterns: for the crowned phthalocyanine an orthorhombic cell with: a = 50.77, b = 25, c = 8.7 Å. For its metal picrate complexes, tetragonal structures were found: a = b = 22.76, c = 12.99 Å (K+-complex); a = b = 29.44, c = 10.63 Å (Cs+-complex); a = b = 29.44, c = 10.40 Å (Rb+-complex). A.c. impedance spectroscopy showed an increase in the electronic conductivity of 2 to 3 powers of ten, if crowned phthalocyanine was aggregated by means of a metal picrate salt. In the K+ complex only electronic conductivity could be detected. The Rb+ and Cs+ complexes exhibited cation conductivity as well." @default.
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- W2109322021 date "1989-06-01" @default.
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- W2109322021 title "Alkali Metal Picrate Complexes of “Crowned”-Phthalocyanines. Solid State Structures and Electrical Properties" @default.
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- W2109322021 doi "https://doi.org/10.1002/bbpc.19890930610" @default.
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