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- W2109361724 abstract "The palladium complexes [Pd(PPh3)(aryl)LOR] (aryl = Ph, p-tolyl; LOR¯ = [(C5H5)Co{P(OR)2O}3]¯, R = Me, Pri) have been prepared by reaction of [PdI(aryl)(tmeda)] (tmeda = N,N,N′,N′-tetramethyl-ethylenediamine) with the silver salts AgLOR in the presence of PPh3. The complexes [Pd(PPh3)(aryl)LOR] rapidly and reversibly insert carbon monoxide to yield the aroyl palladium complexes [Pd(PPh3)(C(O)- p-tolyl)LOR] (R = Me, Pri ). The palladium iodide complex [PdI(p-tolyl)(tmeda)] and the silver salt AgLOR in the absence of PPh3 form an unusual adduct [(p-tolyl)(tmeda)Pd(µ2-I)AgLOMe] that contains a short silver-iodide bond (Ag-I 2 · 703(1) Å). The silver-palladium bond is bridged by iodine (Pd-Ag 3 · 011(1), Pd{I 2 · 5934(9) Å) and the silver atom is coordinated by the tris-chelating oxygen ligand LOMe." @default.
- W2109361724 created "2016-06-24" @default.
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- W2109361724 date "1997-01-01" @default.
- W2109361724 modified "2023-10-11" @default.
- W2109361724 title "Synthesis, X-Ray Crystal Structure and Reactivity of [(tmeda)(p-tolyl)Pd(μ2-I)AgL], an Unusual Silver Iodide Complex; Reversible CO Insertion into the Pd-C Bond of [Pd(PPh3)(p-tolyl)L] (L - = [(C5H5)Co{P(OR)2O}3] - , R = Me, Pri)" @default.
- W2109361724 cites W1984969847 @default.
- W2109361724 doi "https://doi.org/10.1071/c97074" @default.
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