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• W2109427073 abstract "The previously reported incommensurately modulated scheelite-like structure KNd(MoO 4 ) 2 has been exploited as a natural (3 + 1)-dimensional superspace model to generate the scheelite-like three-dimensional structure family. Although each member differs in its space-group symmetry, unit-cell parameters and compositions, in (3 + 1)-dimensional space, they share a common superspace group, a common number of building units in the basic unit cell occupying Wyckoff sites with specific coordinates ( x , y , z ) and specific basic unit-cell axial ratios ( c / a , a / b , b / c ) and angles. Variations of the modulation vector q , occupation functions and t 0 are exploited for the derivation. Eight topologically and compositionally different known structures are compared with their models derived from the KNd(MoO 4 ) 2 structure in order to evaluate the capabilities and limitations of the incommensurately modulated structure to act as a superspace generating model. Applications of the KNd(MoO 4 ) 2 structure as a starting model for the refinement and prediction of some other modulated members of the family is also illustrated. The (3 + 1)-dimensional presentation of the scheelite-like structures reveals new structural relations, which remain hidden if only conventional three-dimensional structure descriptions are applied." @default.
• W2109427073 created "2016-06-24" @default.
• W2109427073 creator A5057099418 @default.
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• W2109427073 date "2008-01-17" @default.
• W2109427073 modified "2023-10-12" @default.
• W2109427073 title "Capabilities and limitations of a (3 + <i>d</i>)-dimensional incommensurately modulated structure as a model for the derivation of an extended family of compounds: example of the scheelite-like structures" @default.
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• W2109427073 doi "https://doi.org/10.1107/s010876810705923x" @default.
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