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• W2109472801 abstract "New tetraarylphosphonium (TAP)-supported alkyl- and arylcarbodiimides were synthesized and used as coupling reagents for esterification reactions, amidation reactions and dehydration reactions of hydroxyesters. Taking advantage of the solubility properties imparted by the tetraarylphosphonium unit, a simple precipitation and filtration allowed complete separation of the urea by-products. This paper describes the structure optimization study of the various TAP-supported carbodiimide reagents to obtain the desired reactivity and solubility profile. Furthermore, we have demonstrated that the diimide reagent can be regenerated from the urea to recycle the reagents." @default.
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• W2109472801 date "2008-03-04" @default.
• W2109472801 modified "2023-09-30" @default.
• W2109472801 title "Tetraarylphosphonium-Supported Carbodiimide Reagents: Synthesis, Structure Optimization and Applications" @default.
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• W2109472801 doi "https://doi.org/10.1021/jo702417v" @default.
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