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- W2109494997 abstract "Abstract Pentafluorophenylammonium trifluoromethanesulfonimide (C 6 F 5 N + H 3 ⋅NTf 2 − ) promotes Mukaiyama aldol and Mannich reactions using ketene silyl acetals with ketones and oxime ethers, respectively. The present robust method is mild, but powerful enough to utilize less accessible electrophiles such as enolizable ketones and oxime ethers to produce a variety of β‐hydroxy esters and β‐alkoxyamino esters, respectively. Mechanistic investigation revealed in situ generation of trimethylsilyl bistriflimide [Tf 2 N(TMS)], the truly active catalyst, which was supported by rational 1 H NMR measurements." @default.
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- W2109494997 date "2010-05-03" @default.
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- W2109494997 title "Pentafluorophenylammonium Trifluoromethanesulfonimide: Mild, Powerful, and Robust Catalyst for Mukaiyama Aldol and Mannich Reactions between Ketene Silyl Acetals and Ketones or Oxime Ethers" @default.
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- W2109494997 doi "https://doi.org/10.1002/adsc.200900869" @default.
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