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- W2109559122 abstract "Poly(p-dioxanone)-block-polyethylene glycol diblock copolymers functionalized with pyrene moieties (Py-PPDO-b-PEG) at the chain ends of PPDO blocks were synthesized for preparing anisotropic micelles with improved stability. The micellization and crystallization of the copolymers were investigated by nano differential scanning calorimetry (Nano DSC), transmission electron microscopy (TEM), UV–vis spectrophotometery, fluorophotometer, and dynamic light scattering (DLS), respectively. The results indicated that the aggregation of pyrene induced by intermolecular interaction lead to micellization of Py-PPDO-b-PEG at much lower concentrations than those of PPDO-b-PEG copolymers without pyrene moieties. The aggregation of pyrene moieties may also serve as nucleation agent and therefore enhance the crystallization rate of PPDO blocks. Fluorescence measurements by using Nile Red as the fluorescent agent indicated that the micelles of Py-PPDO-b-PEG have high stability and load capacity for hydrophobic molecules." @default.
- W2109559122 created "2016-06-24" @default.
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- W2109559122 date "2014-10-01" @default.
- W2109559122 modified "2023-10-18" @default.
- W2109559122 title "Crystallization induced micellization of poly(p-dioxanone)-block-polyethylene glycol diblock copolymer functionalized with pyrene moiety" @default.
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- W2109559122 doi "https://doi.org/10.1016/j.cclet.2014.07.009" @default.
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