Matches in SemOpenAlex for { <https://semopenalex.org/work/W2109663105> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2109663105 endingPage "2165" @default.
- W2109663105 startingPage "2158" @default.
- W2109663105 abstract "Partition coefficients for a number of varied compounds were determined for the n-heptane–methanol and n-heptane–DMF partition systems and used to derive a general model for the distribution of neutral compounds in the biphasic systems. The partition coefficient, log Kp, was correlated through the solvation parameter model giving log Kp = –0.056 + 0.164E–0.620S–1.337A–0.957B + 0.507V for the n-heptane-methanol system with a multiple correlation coefficient of 0.986, standard error of the estimate 0.086, and Fischer statistic 413 for 65 compounds. For n-heptane–DMF, the model is log Kp = 0.065 + 0.030E–1.405S–2.039A–0.806B + 0.721V with a multiple correlation coefficient of 0.991, standard error of the estimate 0.080, and Fischer statistic 560 for 59 compounds. In the models the solute descriptors are excess molar refraction E, dipolarity/polarizability S, overall hydrogen bond acidity, and basicity A and B, respectively, and McGowan's characteristic volume V. Either model is expected to be able to estimate further values of the partition coefficient to about 0.08 log units and is applicable to a wide range of compounds. Applications include the choice of partitioning systems for sample clean-up, countercurrent chromatography, and estimation of solute descriptors for water insoluble or unstable compounds." @default.
- W2109663105 created "2016-06-24" @default.
- W2109663105 creator A5030560376 @default.
- W2109663105 creator A5042984744 @default.
- W2109663105 date "2006-09-01" @default.
- W2109663105 modified "2023-09-23" @default.
- W2109663105 title "Distribution of neutral organic compounds betweenn-heptane and methanol orN,N-dimethylformamide" @default.
- W2109663105 cites W1971580788 @default.
- W2109663105 cites W1987748440 @default.
- W2109663105 cites W1987830966 @default.
- W2109663105 cites W1990987574 @default.
- W2109663105 cites W2005020926 @default.
- W2109663105 cites W2012898602 @default.
- W2109663105 cites W2013521856 @default.
- W2109663105 cites W2013676016 @default.
- W2109663105 cites W2014864996 @default.
- W2109663105 cites W2016579632 @default.
- W2109663105 cites W2021415426 @default.
- W2109663105 cites W2047847597 @default.
- W2109663105 cites W2054800746 @default.
- W2109663105 cites W2061026826 @default.
- W2109663105 cites W2067543159 @default.
- W2109663105 cites W2068103717 @default.
- W2109663105 cites W2073445328 @default.
- W2109663105 cites W2087150137 @default.
- W2109663105 cites W2090722216 @default.
- W2109663105 cites W2092739992 @default.
- W2109663105 cites W383924353 @default.
- W2109663105 doi "https://doi.org/10.1002/jssc.200600131" @default.
- W2109663105 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17069245" @default.
- W2109663105 hasPublicationYear "2006" @default.
- W2109663105 type Work @default.
- W2109663105 sameAs 2109663105 @default.
- W2109663105 citedByCount "26" @default.
- W2109663105 countsByYear W21096631052012 @default.
- W2109663105 countsByYear W21096631052013 @default.
- W2109663105 countsByYear W21096631052014 @default.
- W2109663105 countsByYear W21096631052015 @default.
- W2109663105 countsByYear W21096631052017 @default.
- W2109663105 countsByYear W21096631052020 @default.
- W2109663105 countsByYear W21096631052021 @default.
- W2109663105 crossrefType "journal-article" @default.
- W2109663105 hasAuthorship W2109663105A5030560376 @default.
- W2109663105 hasAuthorship W2109663105A5042984744 @default.
- W2109663105 hasConcept C105795698 @default.
- W2109663105 hasConcept C113196181 @default.
- W2109663105 hasConcept C139287275 @default.
- W2109663105 hasConcept C148093993 @default.
- W2109663105 hasConcept C178790620 @default.
- W2109663105 hasConcept C185592680 @default.
- W2109663105 hasConcept C192552737 @default.
- W2109663105 hasConcept C2777854178 @default.
- W2109663105 hasConcept C2779607525 @default.
- W2109663105 hasConcept C2780092901 @default.
- W2109663105 hasConcept C2780471494 @default.
- W2109663105 hasConcept C32909587 @default.
- W2109663105 hasConcept C33923547 @default.
- W2109663105 hasConcept C43617362 @default.
- W2109663105 hasConceptScore W2109663105C105795698 @default.
- W2109663105 hasConceptScore W2109663105C113196181 @default.
- W2109663105 hasConceptScore W2109663105C139287275 @default.
- W2109663105 hasConceptScore W2109663105C148093993 @default.
- W2109663105 hasConceptScore W2109663105C178790620 @default.
- W2109663105 hasConceptScore W2109663105C185592680 @default.
- W2109663105 hasConceptScore W2109663105C192552737 @default.
- W2109663105 hasConceptScore W2109663105C2777854178 @default.
- W2109663105 hasConceptScore W2109663105C2779607525 @default.
- W2109663105 hasConceptScore W2109663105C2780092901 @default.
- W2109663105 hasConceptScore W2109663105C2780471494 @default.
- W2109663105 hasConceptScore W2109663105C32909587 @default.
- W2109663105 hasConceptScore W2109663105C33923547 @default.
- W2109663105 hasConceptScore W2109663105C43617362 @default.
- W2109663105 hasIssue "14" @default.
- W2109663105 hasLocation W21096631051 @default.
- W2109663105 hasLocation W21096631052 @default.
- W2109663105 hasOpenAccess W2109663105 @default.
- W2109663105 hasPrimaryLocation W21096631051 @default.
- W2109663105 hasRelatedWork W1969521597 @default.
- W2109663105 hasRelatedWork W2016179248 @default.
- W2109663105 hasRelatedWork W2020401131 @default.
- W2109663105 hasRelatedWork W2032270709 @default.
- W2109663105 hasRelatedWork W2046294178 @default.
- W2109663105 hasRelatedWork W2060196767 @default.
- W2109663105 hasRelatedWork W2080213998 @default.
- W2109663105 hasRelatedWork W2081506999 @default.
- W2109663105 hasRelatedWork W2738427321 @default.
- W2109663105 hasRelatedWork W2752948987 @default.
- W2109663105 hasVolume "29" @default.
- W2109663105 isParatext "false" @default.
- W2109663105 isRetracted "false" @default.
- W2109663105 magId "2109663105" @default.
- W2109663105 workType "article" @default.