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- W2109698522 abstract "Effect of the granulation process onto the thermodynamic and kinetic sorption parameters of two basic dyes (Basic Yellow 28-BY 28 and Basic Green 4-BG 4) was evaluated in the present work. The charge surface properties of the surfactant-modified aluminium-pillared clay (CTAB-Al-Mont-PILC) particles were not modified, and the isoelectric point remains constant after high shear wet granulation. The Gibbs free energy of both BY 28 and BG 4 sorption was negative and decreased with the granulation; the endothermic nature of the sorption process was confirmed by the positive values of ΔH°. Adsorption kinetics of the two dyes, studied at pH 6 and 150 mg L−1, follow the pseudo-first order kinetic model with observed rate constants of 2.5–4.2 × 10−2 min−1. The intraparticle diffusion model, proposed by Weber and Morris, was applied, and the intraparticle plots revealed three distinct sections representing external mass transfer, intraparticle diffusion and adsorption/desorption equilibrium. Diffusion coefficients, calculated from the Boyd kinetic equation, increased with the granulation and the particle size. Pseudo-first order kinetic constants, intraparticle diffusion rate constants and diffusion coefficients were determined for two other initial concentrations (50 and 100 mg L−1) and include in a statistical study to evaluate the impact of granulation and initial concentration on the kinetic parameters. Kruskal–Wallis tests, Spearman’s rank order correlation and factor analysis revealed a correlation between (i) the diffusion coefficients and granulation, and between (ii) the intraparticle diffusion rate constants and initial concentration." @default.
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- W2109698522 date "2012-09-01" @default.
- W2109698522 modified "2023-10-12" @default.
- W2109698522 title "Sorption of basic dyes onto granulated pillared clays: Thermodynamic and kinetic studies" @default.
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- W2109698522 doi "https://doi.org/10.1016/j.jcis.2012.05.045" @default.
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