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- W2109785363 abstract "A stable exciton-blocking layer (EBL) with rigid ball-like 4-hydroxy-8-methyl-1,5-naphthyridine aluminium chelate (AlmND3) has been newly developed for organic photovoltaics (OPVs) based on a double-heterostructure of pentacene/C60/EBL. Unlike the common EBL materials, such as tris-(8-hydroxyquinoline)aluminium (Alq3) and bathocuproine (BCP), AlmND3 exhibits a relatively high electron mobility (∼10−4 cm2 V−1 s−1 at the electric field of 6.4 × 105 V cm−1) and a wide band gap energy (∼3.3 eV) in addition to a high glass transition temperature (Tg ∼ 194 °C). Having such EBL between active region (pentacene/C60) and the metal cathode, pristine device performances were comparable with those of BCP-based OPV due to its high mobility and wide band gap energy. Moreover, due to its significantly higher Tg than that of BCP, an extended lifetime performance was observed for AlmND3-based OPV, compared with the BCP-based OPV aged at the elevated temperature of 75 °C." @default.
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- W2109785363 date "2010-01-01" @default.
- W2109785363 modified "2023-09-27" @default.
- W2109785363 title "4-Hydroxy-8-methyl-1,5-naphthyridine aluminium chelate: a morphologically stable and efficient exciton-blocking material for organic photovoltaics with prolonged lifetime" @default.
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- W2109785363 doi "https://doi.org/10.1039/c0jm01049a" @default.
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