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- W2109803784 abstract "A liquid-crystalline octapode, formed by laterally connecting calamitic mesogens to an inorganic silsesquioxane cube through flexible siloxane spacers, is studied using polarized light microscopy, differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The studies are extended to mixtures of the octapode with the respective monomer mesogens. The monomer and the octapode show a nematic phase. At lower temperatures, the octapode exhibits additionally a columnar hexagonal phase (6 lattice), which, on further cooling, undergoes a transition to a columnar rectangular phase (2 lattice). A similar phase-transition sequence is observed for mixtures of the octapode with moderate concentrations of the monomer. The columnar-columnar transition is discussed combining XRD and DSC results, and a possible model of the molecular self-organization is presented." @default.
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- W2109803784 date "2007-01-01" @default.
- W2109803784 modified "2023-10-16" @default.
- W2109803784 title "Columnar phase structures of an organic–inorganic hybrid functionalized with eight calamitic mesogens" @default.
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- W2109803784 doi "https://doi.org/10.1039/b617696h" @default.
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