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- W2109884920 abstract "A series of ϵ-InxFe2–xO3 nanorods are prepared by combining the reverse-micelle and the sol–gel methods. Metal replacement was achieved in the region of 0 ≤ x ≤ 0.24. The crystal structures are orthorhombic structures (space group: Pna21), which are pyroelectric with an electric polarization along the c axis. The transmission electron microscopy images show that the particle sizes are (80 ± 40) × (23 ± 5) nm (x = 0), (65 ± 30) × (30 ± 10) nm (x = 0.12), and (80 ± 40) × (35 ± 15) nm (x = 0.24). The magnetization versus temperature curves of the samples with x = 0, x = 0.12, and x = 0.24 show spontaneous magnetization with Curie temperatures of 495 K, 456 K, and 414 K, respectively. Their coercive fields at 300 K are 20 kOe (x = 0), 14 kOe (x = 0.12), and 9 kOe (x = 0.24). These samples show a spin reorientation with reorientation temperatures (Tp) of 102 K (x = 0), 149 K (x = 0.12), and 180 K (x = 0.24). In particular, the samples with x = 0.12 and x = 0.24 show antiferromagnetic behavior below Tp. This series of ϵ-InxFe2–xO3 is the first example of a pyroelectric material that exhibits a phase transition between ferrimagnetism and antiferromagnetism." @default.
- W2109884920 created "2016-06-24" @default.
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- W2109884920 date "2007-08-08" @default.
- W2109884920 modified "2023-10-17" @default.
- W2109884920 title "Synthesis, Crystal Structure, and Magnetic Properties of ϵ-In<sub> <i>x</i> </sub> Fe<sub>2-</sub> <sub> <i>x</i> </sub> O<sub>3</sub> Nanorod-Shaped Magnets" @default.
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- W2109884920 doi "https://doi.org/10.1002/adfm.200600581" @default.
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