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- W2110085024 abstract "Graft copolymerization of acrylonitrile, methyl methacrylate, and vinyl acetate on bleached holocellulose initiated by ceric ions in aqueous medium was studied at 29°C. The extent of graft copolymer formation was poly(methyl methacrylate) > polyacrylonitrile > poly(vinyl acetate), indicating the influence of polarity of monomer on graft copolymerization. It was found that, although the molecular weights of the grafted polyacrylonitrile copolymer were lower than the values obtained for poly(methyl methacrylate), the latter was less frequently incorporated on the cellulosic backbone polymer than the polyacrylonitrile grafts. The marked reductions in graft level associated with thiolation of the cellulosic material suggest that hydrogen abstraction reactions from carbon atom carrying hydroxyl groups may not be important in graft copolymer formation." @default.
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- W2110085024 date "1989-02-05" @default.
- W2110085024 modified "2023-09-27" @default.
- W2110085024 title "Studies in the graft copolymerization of vinyl monomers on cellulosic materials" @default.
- W2110085024 doi "https://doi.org/10.1002/app.1989.070370509" @default.
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