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- W2110106198 abstract "We have synthesized CdSe nanocrystals (NCs) possessing a trioctylphosphine surface passivation layer and modified with amphiphilic molecules to form a surface bilayer. The NCs covered with single amphiphiles are not stable in aqueous solution, but a mixed amphiphilic system is shown to provide stability in solution over several months. The solutions of the modified NCs were characterized by UV-Vis absorbance, photoluminescence, and transmission electron microscopy. An electrophoretic study revealed two operational modes. The first relies on the enrichment of NCs using a micellar plug as a tool. The accumulation of NCs at the plug-electrolyte buffer interface results in a sharp peak. By controlling the electrophoretic conditions, nanocrystals were forced to exit a micellar plug into an electrolyte buffer. We conclude that a system consisting of modified nanocrystals and a micellar plug can act as a mixed pseudomicellar system, where modified nanocrystals play the role of pseudomicelles." @default.
- W2110106198 created "2016-06-24" @default.
- W2110106198 creator A5037575674 @default.
- W2110106198 creator A5043797229 @default.
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- W2110106198 date "2011-11-04" @default.
- W2110106198 modified "2023-09-27" @default.
- W2110106198 title "Characterization of CdSe nanocrystals coated with amphiphiles. A capillary electrophoresis study" @default.
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- W2110106198 doi "https://doi.org/10.1007/s00604-011-0727-8" @default.
- W2110106198 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3267930" @default.
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