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• W2110110229 abstract "Ortho-benzoyltrimethylanilinium tetrafluoroborate efficiently photo-cyclizes by triplet state δ-hydrogen abstraction to the 1,1-dimethyl-3-hydroxy-3-phenyl-2,3-dihydroindolium salt both in acetonitrile solution and as a solid. Ortho-benzoyI-N,N-dibenzylaniline hydrochloride photocyclizes in acetonitrile to N-benzyl-2,3-diphenylindole. The rate constant for δ-hydrogen abstraction is high thanks to a favorable geometry but rapid internal quenching lowers the quantum yield to only 0.02. Both reactions proceed essentially quantitatively." @default.
• W2110110229 created "2016-06-24" @default.
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• W2110110229 date "1991-08-01" @default.
• W2110110229 modified "2023-10-14" @default.
• W2110110229 title "Photocyclization of ortho-benzoyl N-alkylanilinium ions" @default.
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• W2110110229 doi "https://doi.org/10.1016/0040-4039(91)80588-w" @default.
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