FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2110122980> ?p ?o ?g. }

• W2110122980 endingPage "2140" @default.
• W2110122980 startingPage "2140" @default.
• W2110122980 abstract "We report the synthesis and self assembly of amphiphilic block copolymers based on poly(dimethylsiloxane) and poly(2-(dimethylamino)ethyl acrylate) (PDMS-b-PDMAEA). We consider the self-catalyzed hydrolysis of PDMAEA in aqueous solution, and its effect on the self-assembly of the amphiphilic copolymer by investigating poly(dimethylsiloxane)-b-[poly(2-dimethylamino)ethyl acrylate)-co-poly(acrylic acid)] (PDMS-b-(PDMAEA-co-PAA)), obtained from hydrolysis of PDMAEA, and poly(dimethylsiloxane)-b-poly(2-(trimethylammonium iodide)ethyl acrylate) (PDMS-b-PTMAIEA), obtained from quaternization of PDMAEA. We observe that the thermal properties and self-assembly behavior in water of these amphiphilic diblock copolymers depend on the structure of the hydrophilic block, and are strongly influence by hydrolysis of the PDMAEA block. Self-assembly in aqueous solution leads to the formation of spherical micellar structures with diameters between 40 and 70 nm, which were investigated by dynamic light scattering (DLS) and transmission electron microscope (TEM). PDMS-b-(PDMAEA-co-PAA) is shown to be pH responsive, and behaves as a highly negatively charged polymer at high pH values (pH > 10) and as a highly positively charged polymer at low pH values (pH < 2). Critical micelle concentrations (cmc) of the amphiphilic block copolymers were determined by fluorescence measurement with N-phenyl-1-naphthylamine (PNA) as a fluorescence probe. Surprisingly, surface tension measurements suggest that PDMS-b-PTMAIEA is “non-surface active”, forming micelles in bulk solution instead of adsorbing at the air–water interface to form a Gibbs monolayer, even when the polymer concentration was over 100 times above its cmc value. This remarkable behavior is consistent with recent reports that suggest that “non-surface activity” can be observed for both cationic and anionic amphiphilic diblock copolymers due to the effect of image charge repulsion at the air–water interface." @default.
• W2110122980 created "2016-06-24" @default.
• W2110122980 creator A5012639933 @default.
• W2110122980 creator A5014057252 @default.
• W2110122980 creator A5065528669 @default.
• W2110122980 creator A5066176306 @default.
• W2110122980 creator A5076529713 @default.
• W2110122980 date "2013-01-01" @default.
• W2110122980 modified "2023-10-12" @default.
• W2110122980 title "Unexpected behavior of polydimethylsiloxane/poly(2-(dimethylamino)ethyl acrylate) (charged) amphiphilic block copolymers in aqueous solution" @default.
• W2110122980 cites W15140341 @default.
• W2110122980 cites W1966993500 @default.
• W2110122980 cites W1968484078 @default.
• W2110122980 cites W1968928912 @default.
• W2110122980 cites W1973427030 @default.
• W2110122980 cites W1977040267 @default.
• W2110122980 cites W1977894780 @default.
• W2110122980 cites W1978688666 @default.
• W2110122980 cites W1978992591 @default.
• W2110122980 cites W1981935169 @default.
• W2110122980 cites W1983892844 @default.
• W2110122980 cites W1987022648 @default.
• W2110122980 cites W1988129684 @default.
• W2110122980 cites W1989845456 @default.
• W2110122980 cites W1997961069 @default.
• W2110122980 cites W1998497843 @default.
• W2110122980 cites W2010700081 @default.
• W2110122980 cites W2016402410 @default.
• W2110122980 cites W2016726700 @default.
• W2110122980 cites W2018046767 @default.
• W2110122980 cites W2022254502 @default.
• W2110122980 cites W2027241082 @default.
• W2110122980 cites W2031732057 @default.
• W2110122980 cites W2039760408 @default.
• W2110122980 cites W2041671510 @default.
• W2110122980 cites W2041681472 @default.
• W2110122980 cites W2044996782 @default.
• W2110122980 cites W2046096404 @default.
• W2110122980 cites W2047471931 @default.
• W2110122980 cites W2047818484 @default.
• W2110122980 cites W2051373542 @default.
• W2110122980 cites W2055764000 @default.
• W2110122980 cites W2062883149 @default.
• W2110122980 cites W2065315301 @default.
• W2110122980 cites W2071248468 @default.
• W2110122980 cites W2073186779 @default.
• W2110122980 cites W2076271218 @default.
• W2110122980 cites W2076552740 @default.
• W2110122980 cites W2083476946 @default.
• W2110122980 cites W2087809351 @default.
• W2110122980 cites W2089409056 @default.
• W2110122980 cites W2092886522 @default.
• W2110122980 cites W2104516877 @default.
• W2110122980 cites W2117412515 @default.
• W2110122980 cites W2129135711 @default.
• W2110122980 cites W2133053342 @default.
• W2110122980 cites W2137607015 @default.
• W2110122980 cites W2139754635 @default.
• W2110122980 cites W2150184000 @default.
• W2110122980 cites W2150970857 @default.
• W2110122980 cites W2156616321 @default.
• W2110122980 cites W2160958269 @default.
• W2110122980 cites W2162656482 @default.
• W2110122980 cites W2216275186 @default.
• W2110122980 cites W4252446124 @default.
• W2110122980 doi "https://doi.org/10.1039/c3py21038c" @default.
• W2110122980 hasPublicationYear "2013" @default.
• W2110122980 type Work @default.
• W2110122980 sameAs 2110122980 @default.
• W2110122980 citedByCount "50" @default.
• W2110122980 countsByYear W21101229802013 @default.
• W2110122980 countsByYear W21101229802014 @default.
• W2110122980 countsByYear W21101229802015 @default.
• W2110122980 countsByYear W21101229802016 @default.
• W2110122980 countsByYear W21101229802017 @default.
• W2110122980 countsByYear W21101229802018 @default.
• W2110122980 countsByYear W21101229802019 @default.
• W2110122980 countsByYear W21101229802020 @default.
• W2110122980 countsByYear W21101229802021 @default.
• W2110122980 countsByYear W21101229802022 @default.
• W2110122980 countsByYear W21101229802023 @default.
• W2110122980 crossrefType "journal-article" @default.
• W2110122980 hasAuthorship W2110122980A5012639933 @default.
• W2110122980 hasAuthorship W2110122980A5014057252 @default.
• W2110122980 hasAuthorship W2110122980A5065528669 @default.
• W2110122980 hasAuthorship W2110122980A5066176306 @default.
• W2110122980 hasAuthorship W2110122980A5076529713 @default.
• W2110122980 hasConcept C11268172 @default.
• W2110122980 hasConcept C14631669 @default.
• W2110122980 hasConcept C155672457 @default.
• W2110122980 hasConcept C15920480 @default.
• W2110122980 hasConcept C171250308 @default.
• W2110122980 hasConcept C178790620 @default.
• W2110122980 hasConcept C184651966 @default.
• W2110122980 hasConcept C185592680 @default.
• W2110122980 hasConcept C188027245 @default.
• W2110122980 hasConcept C188109995 @default.
• W2110122980 hasConcept C192562407 @default.

• next