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- W2110128510 abstract "The synthesis of 1,2-epoxy-3-nitropropane (ENP) was improved so that this monomer could be obtained in a pure, stable form with an acceptable yield. Anionic polymerization even using milder conditions causes isomerization of ENP into nitroallylic alcohol. Cationic polymerization using a classical initiator produces a mixture of compounds of low molecular weight. We have studied in detail the cationic polymerization of ENP in the presence of a diol such as ethylene glycol (“Activated Monomer Mechanism”): only the first two steps follow this latter, but a competitive mechanism takes over rapidly which limits severely the molecular weight of the products: this mechanism was analyzed." @default.
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- W2110128510 date "1993-07-01" @default.
- W2110128510 modified "2023-10-12" @default.
- W2110128510 title "Synthesis and ionic polymerization of 1,2-epoxy-3-nitropropane" @default.
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- W2110128510 doi "https://doi.org/10.1002/masy.19930730112" @default.
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