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- W2110147861 abstract "Abstract The direct thiolation of phenylpyrazole with disulfide using the FeBr3/I2 complex as the catalyst in MeCN at 80 °C was reported. With the optimum conditions, several fipronil derivatives of 4-sulfenylpyrazole were synthesized by the reaction of 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl-lH-pyrazole-3-arbonitrile (1a) with disulfides (2) in moderate to good yields. The coupling reaction with diaryl diselane also occurred under similar conditions." @default.
- W2110147861 created "2016-06-24" @default.
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- W2110147861 date "2013-01-29" @default.
- W2110147861 modified "2023-09-24" @default.
- W2110147861 title "ChemInform Abstract: Iron-Catalyzed Direct Sulfenylation and Selenylations of Phenylpyrazoles: Synthesis of Fipronil Derivatives with Disulfides Promoted by a Catalytic Amount of Iodine." @default.
- W2110147861 cites W2952441992 @default.
- W2110147861 doi "https://doi.org/10.1002/chin.201305089" @default.
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