FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2110167312> ?p ?o ?g. }

• W2110167312 endingPage "223" @default.
• W2110167312 startingPage "215" @default.
• W2110167312 abstract "The chlorination of singly and multiply charged C60 cations has been investigated using the selected-ion flow tube (SIFT) technique with chlorinated ethylenes as possible chlorinating agents. Observations are reported for the reactions of C60·+, C602+, and C60·3+ with CH2CHCl, CH2CCl2, trans-CHClCHCl, cis-CHClCHCl, CHClCCl2 and CCl2CCl2 at room temperature (295 ± 2 K) in helium at a total pressure of 0.35 ± 0.02 Torr. The results generally are consistent with previous studies of the reactivities of these three ionized states of C60 under SIFT conditions. C60·+ was observed not to react in any way and C60·3+ reacted exclusively by rapid electron transfer, k > 1.0 × 10−9 cm3 molecule−1 s−1. C602+ was observed to be less reactive with values of k in the range from 1.5 × 10−12 to 1.6 × 10−10 cm3 molecule−1 s−1 and exhibited three different types of reaction channels: electron transfer, adduct formation, and (Cl)2 transfer. The latter channel was the only chlorination channel observed and occurred exclusively with the cis and trans isomers of 1,2-dichloroethylene, but in competition with adduct formation. The variation observed in the occurrence of these three channels with charge state is consistent with what is now known about the role of charge state in promoting bond formation with the C60 surface and the role of coulombic repulsion between product ions in preventing electron transfer. A bimolecular reaction of the C60 (trans-HClCCHCl)2+ adduct ion with trans-1,2-dichloroethylene was observed leading to the elimination of acetylene or chlorine. Higher-order sequential additions to C602+ were seen with vinyl chloride, 1,1-dichloroethylene, and trichloroethylene and these are proposed to proceed by “ball-and-chain” polymerization." @default.
• W2110167312 created "2016-06-24" @default.
• W2110167312 creator A5043332857 @default.
• W2110167312 creator A5043954197 @default.
• W2110167312 creator A5045031281 @default.
• W2110167312 creator A5056135001 @default.
• W2110167312 creator A5079326920 @default.
• W2110167312 date "1999-09-01" @default.
• W2110167312 modified "2023-09-26" @default.
• W2110167312 title "Selected-ion flow tube studies of reactions of C60n+ (n = 1, 2, 3) with chlorinated ethylenes" @default.
• W2110167312 cites W1963887946 @default.
• W2110167312 cites W1966758737 @default.
• W2110167312 cites W1998246830 @default.
• W2110167312 cites W2020856745 @default.
• W2110167312 cites W2032172214 @default.
• W2110167312 cites W2034789535 @default.
• W2110167312 cites W2049852177 @default.
• W2110167312 cites W2062317131 @default.
• W2110167312 cites W2065847284 @default.
• W2110167312 cites W2075709963 @default.
• W2110167312 cites W2114711771 @default.
• W2110167312 cites W2120160688 @default.
• W2110167312 cites W2122552034 @default.
• W2110167312 cites W2134132857 @default.
• W2110167312 cites W2170761067 @default.
• W2110167312 cites W2211630414 @default.
• W2110167312 cites W283621144 @default.
• W2110167312 cites W2950472896 @default.
• W2110167312 doi "https://doi.org/10.1016/s1387-3806(99)00107-4" @default.
• W2110167312 hasPublicationYear "1999" @default.
• W2110167312 type Work @default.
• W2110167312 sameAs 2110167312 @default.
• W2110167312 citedByCount "11" @default.
• W2110167312 countsByYear W21101673122022 @default.
• W2110167312 crossrefType "journal-article" @default.
• W2110167312 hasAuthorship W2110167312A5043332857 @default.
• W2110167312 hasAuthorship W2110167312A5043954197 @default.
• W2110167312 hasAuthorship W2110167312A5045031281 @default.
• W2110167312 hasAuthorship W2110167312A5056135001 @default.
• W2110167312 hasAuthorship W2110167312A5079326920 @default.
• W2110167312 hasConcept C108204754 @default.
• W2110167312 hasConcept C123669783 @default.
• W2110167312 hasConcept C145148216 @default.
• W2110167312 hasConcept C178790620 @default.
• W2110167312 hasConcept C185592680 @default.
• W2110167312 hasConcept C32909587 @default.
• W2110167312 hasConcept C71240020 @default.
• W2110167312 hasConcept C75079739 @default.
• W2110167312 hasConcept C75473681 @default.
• W2110167312 hasConceptScore W2110167312C108204754 @default.
• W2110167312 hasConceptScore W2110167312C123669783 @default.
• W2110167312 hasConceptScore W2110167312C145148216 @default.
• W2110167312 hasConceptScore W2110167312C178790620 @default.
• W2110167312 hasConceptScore W2110167312C185592680 @default.
• W2110167312 hasConceptScore W2110167312C32909587 @default.
• W2110167312 hasConceptScore W2110167312C71240020 @default.
• W2110167312 hasConceptScore W2110167312C75079739 @default.
• W2110167312 hasConceptScore W2110167312C75473681 @default.
• W2110167312 hasIssue "1-3" @default.
• W2110167312 hasLocation W21101673121 @default.
• W2110167312 hasOpenAccess W2110167312 @default.
• W2110167312 hasPrimaryLocation W21101673121 @default.
• W2110167312 hasRelatedWork W1964636348 @default.
• W2110167312 hasRelatedWork W1976235000 @default.
• W2110167312 hasRelatedWork W1987790918 @default.
• W2110167312 hasRelatedWork W2005064548 @default.
• W2110167312 hasRelatedWork W2024145292 @default.
• W2110167312 hasRelatedWork W2086191285 @default.
• W2110167312 hasRelatedWork W2397405551 @default.
• W2110167312 hasRelatedWork W2463708132 @default.
• W2110167312 hasRelatedWork W2793312104 @default.
• W2110167312 hasRelatedWork W2506236844 @default.
• W2110167312 hasVolume "192" @default.
• W2110167312 isParatext "false" @default.
• W2110167312 isRetracted "false" @default.
• W2110167312 magId "2110167312" @default.
• W2110167312 workType "article" @default.