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- W2110170720 abstract "A new nanosized catalytic system has been developed for convenient preparation of β-vinyl sulfides H2CC(SAr)R with high yields (79−98%) and excellent selectivity (>98:2). Inexpensive and easily available Ni(acac)2 was used as catalyst precursor. Solvent-free conditions were combined with high atom efficiency of the ArSH addition reaction to terminal alkynes (HC⋮C−R) in order to create an environmentally friendly synthetic procedure. The mechanistic study has indicated that catalytic reaction takes place under heterogeneous conditions with alkyne insertion into the Ni−S bond as a key step." @default.
- W2110170720 created "2016-06-24" @default.
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- W2110170720 date "2006-03-10" @default.
- W2110170720 modified "2023-10-12" @default.
- W2110170720 title "Efficient and Convenient Synthesis of β-Vinyl Sulfides in Nickel-Catalyzed Regioselective Addition of Thiols to Terminal Alkynes under Solvent-Free Conditions" @default.
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- W2110170720 doi "https://doi.org/10.1021/om051105j" @default.
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