Matches in SemOpenAlex for { <https://semopenalex.org/work/W2110183148> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2110183148 endingPage "3725" @default.
- W2110183148 startingPage "3719" @default.
- W2110183148 abstract "The results of a study of the hydrogen reaction (HER) and the hydrogen oxidation reaction (HOR) on the three low-index faces of Pt in alkaline solution are presented. The study features a new method for the use of Pt single crystals in a rotating disk electrode (RDE) configuration. At low negative overpotentials, the order of activity for the HER increased in the sequence (111) < (100) < (110). At low positive overpotentials, the order of activity for the HOR increased in the sequence (111)≈(100)(110). These differences in activity with crystal face are attributed to different states of adsorbed hydrogen and to different effects of these states on the mechanism of the hydrogen reaction. Two different types of adsorbed hydrogen are observed on Pt(hkl) surfaces. A high binding energy state, often referred to as underpotential deposited hydrogen, Hupd, has an inhibiting (site blocking) effect on the rate of the HER and HOR. A low binding energy state is a reaction intermediate at low overpotentials in both the HOR as well as the HER, and is most prevalent on the (110) surface. At high positive overpotentials, in the potential region where adsorption of hydroxy species (OHad) occurs, the effects of surface crystallography on the HOR is attributed to the structural sensitivity of the adsorption of OHad on Pt(hkl), with OHad having an inhibiting effect on the HOR, the inhibition decreasing in the sequence (100)(110) < (111)." @default.
- W2110183148 created "2016-06-24" @default.
- W2110183148 creator A5025607505 @default.
- W2110183148 creator A5041677654 @default.
- W2110183148 creator A5053287842 @default.
- W2110183148 creator A5088146443 @default.
- W2110183148 date "1996-01-01" @default.
- W2110183148 modified "2023-10-01" @default.
- W2110183148 title "Hydrogen electrochemistry on platinum low-index single-crystal surfaces in alkaline solution" @default.
- W2110183148 cites W1967674568 @default.
- W2110183148 cites W1974984468 @default.
- W2110183148 cites W1977338018 @default.
- W2110183148 cites W2005840410 @default.
- W2110183148 cites W2006507218 @default.
- W2110183148 cites W2025955722 @default.
- W2110183148 cites W2046231595 @default.
- W2110183148 cites W2046565700 @default.
- W2110183148 cites W2065456878 @default.
- W2110183148 cites W2067415689 @default.
- W2110183148 cites W2068837243 @default.
- W2110183148 cites W2083445012 @default.
- W2110183148 cites W2088089565 @default.
- W2110183148 cites W2156227233 @default.
- W2110183148 cites W2171613439 @default.
- W2110183148 cites W2950889169 @default.
- W2110183148 cites W2976783901 @default.
- W2110183148 doi "https://doi.org/10.1039/ft9969203719" @default.
- W2110183148 hasPublicationYear "1996" @default.
- W2110183148 type Work @default.
- W2110183148 sameAs 2110183148 @default.
- W2110183148 citedByCount "354" @default.
- W2110183148 countsByYear W21101831482012 @default.
- W2110183148 countsByYear W21101831482013 @default.
- W2110183148 countsByYear W21101831482014 @default.
- W2110183148 countsByYear W21101831482015 @default.
- W2110183148 countsByYear W21101831482016 @default.
- W2110183148 countsByYear W21101831482017 @default.
- W2110183148 countsByYear W21101831482018 @default.
- W2110183148 countsByYear W21101831482019 @default.
- W2110183148 countsByYear W21101831482020 @default.
- W2110183148 countsByYear W21101831482021 @default.
- W2110183148 countsByYear W21101831482022 @default.
- W2110183148 countsByYear W21101831482023 @default.
- W2110183148 crossrefType "journal-article" @default.
- W2110183148 hasAuthorship W2110183148A5025607505 @default.
- W2110183148 hasAuthorship W2110183148A5041677654 @default.
- W2110183148 hasAuthorship W2110183148A5053287842 @default.
- W2110183148 hasAuthorship W2110183148A5088146443 @default.
- W2110183148 hasConcept C113196181 @default.
- W2110183148 hasConcept C147789679 @default.
- W2110183148 hasConcept C150394285 @default.
- W2110183148 hasConcept C161790260 @default.
- W2110183148 hasConcept C17525397 @default.
- W2110183148 hasConcept C178790620 @default.
- W2110183148 hasConcept C179104552 @default.
- W2110183148 hasConcept C185592680 @default.
- W2110183148 hasConcept C2777869211 @default.
- W2110183148 hasConcept C2781060269 @default.
- W2110183148 hasConcept C512968161 @default.
- W2110183148 hasConcept C518104683 @default.
- W2110183148 hasConcept C52859227 @default.
- W2110183148 hasConcept C73922627 @default.
- W2110183148 hasConcept C8010536 @default.
- W2110183148 hasConceptScore W2110183148C113196181 @default.
- W2110183148 hasConceptScore W2110183148C147789679 @default.
- W2110183148 hasConceptScore W2110183148C150394285 @default.
- W2110183148 hasConceptScore W2110183148C161790260 @default.
- W2110183148 hasConceptScore W2110183148C17525397 @default.
- W2110183148 hasConceptScore W2110183148C178790620 @default.
- W2110183148 hasConceptScore W2110183148C179104552 @default.
- W2110183148 hasConceptScore W2110183148C185592680 @default.
- W2110183148 hasConceptScore W2110183148C2777869211 @default.
- W2110183148 hasConceptScore W2110183148C2781060269 @default.
- W2110183148 hasConceptScore W2110183148C512968161 @default.
- W2110183148 hasConceptScore W2110183148C518104683 @default.
- W2110183148 hasConceptScore W2110183148C52859227 @default.
- W2110183148 hasConceptScore W2110183148C73922627 @default.
- W2110183148 hasConceptScore W2110183148C8010536 @default.
- W2110183148 hasIssue "20" @default.
- W2110183148 hasLocation W21101831481 @default.
- W2110183148 hasOpenAccess W2110183148 @default.
- W2110183148 hasPrimaryLocation W21101831481 @default.
- W2110183148 hasRelatedWork W1979768730 @default.
- W2110183148 hasRelatedWork W1984010865 @default.
- W2110183148 hasRelatedWork W2000578039 @default.
- W2110183148 hasRelatedWork W2021876770 @default.
- W2110183148 hasRelatedWork W2035542390 @default.
- W2110183148 hasRelatedWork W2042038334 @default.
- W2110183148 hasRelatedWork W2063826068 @default.
- W2110183148 hasRelatedWork W2270523287 @default.
- W2110183148 hasRelatedWork W2390081673 @default.
- W2110183148 hasRelatedWork W2512456711 @default.
- W2110183148 hasVolume "92" @default.
- W2110183148 isParatext "false" @default.
- W2110183148 isRetracted "false" @default.
- W2110183148 magId "2110183148" @default.
- W2110183148 workType "article" @default.