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- W2110256571 abstract "TiO2 gel obtained by hydrolysis of titanium tetra-n-butoxide was heated at various temperatures, providing poorly crystallized TiO2, disordered anatase and a well crystallized anatase—rutile mixture. Platinum dispersion was obtained on these TiO2 supports by the reduction of platinum—allyl species with H2 at 278 K. These catalysts and a Pt/SiO2-gel sample were used for propene hydrogenation at various temperatures and H2/propene molecular ratios. Fresh and run catalysts were subjected to X-ray diffraction analysis for the study of extant phases and determination of average size of platinum particles. In all cases, results obtained for catalysts as prepared or after H2 treatment at 493 K indicated that the ordinary hydrogenation mechanism was maintained but that important changes of specific catalytic activity were observed, depending on H2 treatment and nature of the support. TiO2 morphology was assumed to be responsible for the specific activity decrease in Pt on the rutile—anatase mixture and for the opposite effect found for platinum on anatase." @default.
- W2110256571 created "2016-06-24" @default.
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- W2110256571 date "1994-12-01" @default.
- W2110256571 modified "2023-09-30" @default.
- W2110256571 title "Propene hydrogenation on low-temperature reduced Pt/TiO2. Effects of TiO2 phases and H2 treatment on specific catalytic activity" @default.
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- W2110256571 doi "https://doi.org/10.1016/0304-5102(94)00130-8" @default.
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