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- W2110257616 abstract "1; R1 = H, R2 = (E)-SiMe3) [86422-21-1] C8H16O2Si (MW 172.33) InChI = 1S/C8H16O2Si/c1-8(9)10-6-5-7-11(2,3)4/h5,7H,6H2,1-4H3/b7-5+ InChIKey = KWDYUHNACUTFNF-FNORWQNLSA-N 2; R1 = H, R2 = (Z)-SiMe3) [86422-22-2] InChI = 1S/C8H16O2Si/c1-8(9)10-6-5-7-11(2,3)4/h5,7H,6H2,1-4H3/b7-5- InChIKey = KWDYUHNACUTFNF-ALCCZGGFSA-N (E + Z) [80401-14-5] InChI = 1S/C8H16O2Si/c1-8(9)10-6-5-7-11(2,3)4/h5,7H,6H2,1-4H3 InChIKey = KWDYUHNACUTFNF-UHFFFAOYSA-N 3; R1 = SiMe3, R2 = H) [80401-11-2] InChI = 1S/C8H16O2Si/c1-6-8(10-7(2)9)11(3,4)5/h6,8H,1H2,2-5H3 InChIKey = IAMQLXWPWSUFPI-UHFFFAOYSA-N (preparation of vinylsilanes via the corresponding allylmetal complexes;1 oxygenated allylsilane reagents for nucleophilic addition and substitution reactions2) Preparative Method: (i) from 3-trimethylsilyl-2-propyn-1-ol by reduction (Sodium Bis(2‐methoxyethoxy)aluminum Hydride (Red-Al), 70%)3 and acetylation (Acetyl Chloride, Pyridine, 78%);4 (ii) from 3-trimethylsilyl-2-propyn-1-ol by reduction (P-2 Raney Nickel, H2, 86%)5 and acetylation; (iii) from allyloxytrimethylsilane by a metalation–rearrangement sequence (t‐Butyllithium, 90%)2a,6 and acetylation (Acetic Anhydride, Triethylamine, 76%).2a Handling, Storage, and Precautions: use in a fume hood." @default.
- W2110257616 created "2016-06-24" @default.
- W2110257616 creator A5013712145 @default.
- W2110257616 date "2001-04-15" @default.
- W2110257616 modified "2023-09-26" @default.
- W2110257616 title "3-Trimethylsilyl-2-propen-1-yl Acetate" @default.
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- W2110257616 doi "https://doi.org/10.1002/047084289x.rt333" @default.
- W2110257616 hasPublicationYear "2001" @default.
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