Matches in SemOpenAlex for { <https://semopenalex.org/work/W2110281666> ?p ?o ?g. }
- W2110281666 endingPage "164" @default.
- W2110281666 startingPage "137" @default.
- W2110281666 abstract "Abstract Simple bond dissociations and hydrogen rearrangements in gaseous cation radicals and even-electron cations can be governed by stereoelectronic effects imposed by control elements. Stereoelectronic effects facilitate dissociations of bonds that are aligned with the control orbital of n- or π-type to allow efficient orbital overlap in the transition state. Ions with unfavorably large dihedral angles between the bond to be broken and the control orbital undergo conformational transformations in order to achieve a stereoelectronically assisted transition state. Stereoelectronic effects are likely to be encountered with rigid polycyclic ions in which fixed dihedral angles are imposed by bond connectivity. Nevertheless, striking stereoelectronic effects have been observed in a few conformationally mobile systems. Several examples of stereo- chemical ion dissociation due to stereoelectronic effects are discussed in this review with the help of experimental energy data, and ab initio, semi-empirical, and empirical-potential (MM2) calculations." @default.
- W2110281666 created "2016-06-24" @default.
- W2110281666 creator A5042952795 @default.
- W2110281666 date "1991-10-01" @default.
- W2110281666 modified "2023-10-18" @default.
- W2110281666 title "Stereoelectronic effects in mass spectrometry" @default.
- W2110281666 cites W1507119163 @default.
- W2110281666 cites W1826361906 @default.
- W2110281666 cites W1967274389 @default.
- W2110281666 cites W1968819744 @default.
- W2110281666 cites W1970431432 @default.
- W2110281666 cites W1972982314 @default.
- W2110281666 cites W1974217520 @default.
- W2110281666 cites W1974767588 @default.
- W2110281666 cites W1980586954 @default.
- W2110281666 cites W1983045790 @default.
- W2110281666 cites W1984217930 @default.
- W2110281666 cites W1987766496 @default.
- W2110281666 cites W1995260899 @default.
- W2110281666 cites W1999619871 @default.
- W2110281666 cites W2005516973 @default.
- W2110281666 cites W2008659504 @default.
- W2110281666 cites W2008984051 @default.
- W2110281666 cites W2009859471 @default.
- W2110281666 cites W2010134093 @default.
- W2110281666 cites W2010575310 @default.
- W2110281666 cites W2019842387 @default.
- W2110281666 cites W2022205739 @default.
- W2110281666 cites W2022286165 @default.
- W2110281666 cites W2022464228 @default.
- W2110281666 cites W2022525163 @default.
- W2110281666 cites W2023109539 @default.
- W2110281666 cites W2025339255 @default.
- W2110281666 cites W2026363039 @default.
- W2110281666 cites W2030230761 @default.
- W2110281666 cites W2032076300 @default.
- W2110281666 cites W2032255479 @default.
- W2110281666 cites W2032858157 @default.
- W2110281666 cites W2034047354 @default.
- W2110281666 cites W2037682587 @default.
- W2110281666 cites W2042031417 @default.
- W2110281666 cites W2045376729 @default.
- W2110281666 cites W2046060468 @default.
- W2110281666 cites W2046238515 @default.
- W2110281666 cites W2048813773 @default.
- W2110281666 cites W2053857296 @default.
- W2110281666 cites W2054667237 @default.
- W2110281666 cites W2055711209 @default.
- W2110281666 cites W2056283825 @default.
- W2110281666 cites W2057017092 @default.
- W2110281666 cites W2058571501 @default.
- W2110281666 cites W2063959801 @default.
- W2110281666 cites W2067529700 @default.
- W2110281666 cites W2068705550 @default.
- W2110281666 cites W2071205305 @default.
- W2110281666 cites W2075862819 @default.
- W2110281666 cites W2077335572 @default.
- W2110281666 cites W2078391246 @default.
- W2110281666 cites W2082986426 @default.
- W2110281666 cites W2083059441 @default.
- W2110281666 cites W2084711908 @default.
- W2110281666 cites W2088615896 @default.
- W2110281666 cites W2096731736 @default.
- W2110281666 cites W2105714584 @default.
- W2110281666 cites W2109492719 @default.
- W2110281666 cites W2109669889 @default.
- W2110281666 cites W2115725620 @default.
- W2110281666 cites W2126111554 @default.
- W2110281666 cites W2146668030 @default.
- W2110281666 cites W2148010053 @default.
- W2110281666 cites W2155392217 @default.
- W2110281666 cites W2161082092 @default.
- W2110281666 cites W2165574400 @default.
- W2110281666 cites W2320040743 @default.
- W2110281666 cites W2339457896 @default.
- W2110281666 cites W2346813395 @default.
- W2110281666 cites W2949558561 @default.
- W2110281666 cites W2950633309 @default.
- W2110281666 cites W2950953675 @default.
- W2110281666 cites W2951107618 @default.
- W2110281666 cites W2951186747 @default.
- W2110281666 cites W2951442845 @default.
- W2110281666 cites W2951696979 @default.
- W2110281666 cites W2953370435 @default.
- W2110281666 cites W3004474606 @default.
- W2110281666 cites W3004925352 @default.
- W2110281666 cites W4236711211 @default.
- W2110281666 cites W4242636966 @default.
- W2110281666 cites W4243481968 @default.
- W2110281666 cites W4255438496 @default.
- W2110281666 doi "https://doi.org/10.1016/0168-1176(91)85030-p" @default.
- W2110281666 hasPublicationYear "1991" @default.
- W2110281666 type Work @default.
- W2110281666 sameAs 2110281666 @default.
- W2110281666 citedByCount "15" @default.
- W2110281666 countsByYear W21102816662017 @default.
- W2110281666 crossrefType "journal-article" @default.
- W2110281666 hasAuthorship W2110281666A5042952795 @default.