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- W2110301527 abstract "Abstract The electrical conductivity and Seebeck coefficient of single crystal calcium titanate were measured as a function of temperature and P H 2 O ⧸ P H 2 . The electrical conductivity was determined at temperatures from 1100° to 1300°C. The P H 2 O ⧸ p H 2 ratio extended from 2 × 10 −4 to 8 × 10 −2 . At 1200°C the electrical conductivity was 3.70 Ω −1 cm −1 at P H 2 O ⧸ P H 2 = 10 −3 and 1.75 Ω −1 cm −1 at p H 2 0 ⧸ p H 2 = 10 −2 ; the Seebeck coefficients were − 500 and − 580μ v°⧸k under the same conditions. The electrical conductivity was proportional to the −1 3 power of P H 2 O P H 2 . The sign of the Seebeck coefficient indicated the majority carriers to be electrons. The results may be described by a majority defect model consisting of doubly ionized oxygen vacancies and electrons. The standard enthalpy of formation was found to be 93,000 ± 4000 cal⧸mol. of oxygen vacancies." @default.
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- W2110301527 date "1969-04-01" @default.
- W2110301527 modified "2023-09-27" @default.
- W2110301527 title "Formation of point defects in calcium titanate" @default.
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- W2110301527 doi "https://doi.org/10.1016/0022-3697(69)90284-4" @default.
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