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- W2110347079 abstract "The dependence of the NO/Ag(111) trapping probability on the orientation of the molecular axis of the approaching molecule has been measured for incident translational energies Ei = 100 and 200 meV and various angles of incidence. It was found, that approaching with the O-end towards the surface results in the highest trapping probability. This steric effect can be induced by an anisotropic repulsion between NO and Ag(111), which yields a higher rotational excitation for the O-end collision, than for the N-end collision. In this way a rotationally mediated adsorption would cause a higher trapping probability for the O-end collision. Although the trapping of NO on our Ag(111) surface is solely a function of Ei the measured steric effect is found to be dependent on Ei cos2θi. This behaviour might be explained by a two-step trapping process for which the incoming orientation is important only to the accommodation of the velocity component perpendicular to the surface." @default.
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- W2110347079 date "1989-11-01" @default.
- W2110347079 modified "2023-09-27" @default.
- W2110347079 title "Dependence of the NO/Ag(111) trapping probability on molecular orientation" @default.
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- W2110347079 doi "https://doi.org/10.1016/0301-0104(89)87151-4" @default.
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