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• W2110348021 abstract "A combination of neutron diffraction and X-ray absorption spectroscopic techniques has been used to investigate the Ti coordination in vitreous K2O· TiO2 · 2SiO2. In the former case, the Tizz.sbnd;O bond lengths have been studied using the technique of isotopic substitution. XANES (X-ray absorption near-edge structure) data indicate that there is little or no evidence for a centre of inversion symmetry at the Ti site in the glass. TiO bond distances derived from neutron diffrraction and EXAFS (extended X-ray absorption fine structure) agree to within 0.03 Å and it is concluded that the Ti is present as TiO5 tetragonal pyramids containing one non-bridging oxygen atom associated witth a titanyl bond (Ti=0 = 1.65 Å). The bridging TiO bond length is 1.96 Å and TiTi correlations occur at 3.4 Å and 6.1 Å." @default.
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• W2110348021 date "1986-01-01" @default.
• W2110348021 modified "2023-10-10" @default.
• W2110348021 title "Neutron diffraction and exafs evidence for TiO5 units in vitreous K2O · TiO2 · 2SiO2" @default.
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• W2110348021 doi "https://doi.org/10.1016/0022-3093(86)90041-4" @default.
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