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- W2110348765 abstract "The properties of the diamond-like carbon (DLC) coatings prepared with the filtered pulsed arc discharge (FPAD) method developed in our laboratory are exceptional; they are highquality (>80% sp diamond bonds), ultra-thick (up to 200 μm) and have excellent adhesion. These features, especially the thickness of the coating, are essential in applications. Typically the thickness and the quality of the DLC coating or thin film are compromised to avoid poor adhesion due to the internal stress in the coating. Superior adhesion is achieved with the FPAD method, where carbon ions have high energies and they form a mixing layer between the substrate and the coating. The deposition process was studied in detail and a simple and fast new method to simultaneously test the adhesion and quality of the DLC coating was developed and is reported in this thesis. Another indication of the exceptionality of the deposition system was obtained when the light emitted by the plasma in the FPAD system was studied with a spectrograph. This revealed that the energies (from Doppler shifts) and charge-states (line spectra of carbon) of the carbon ions differ significantly from those of reported in the literature. The carbon ions in the FPAD plasma have higher energies and higher charge-states than those typically reported for carbon ions. The benefits of using tantalum as an intermediate layer between the substrate material and the DLC coating are discussed in this thesis. The tantalum layer was first introduced as it improved the adhesion and allowed a wider variety of substrate materials to be used. At present, the use of tantalum is recommended to prevent pinhole failure. In a corrosion experiment with tantalum coated and uncoated human hip joint prostheses it was found that when exposed to 10% HCl solution tantalum coating decreased the corrosion rate of CrCoMo acetabular cups by a factor of 10. The modification of the FPAD method to prepare novel DLC-polymer-hybrid coatings is also covered in this thesis. Both the coatings and their deposition method are recent innovations of our research group. In the novel coatings the properties of the polymer and the hard DLC can be combined. Common non-stick polymers, polydimethylsiloxane (PDMS) and polytetrafluoroethylene (PTFE), have been used as the polymer component in the hybrid coatings and as a result coatings that are considerably hard and water and oil repellent have been prepared. The water and oil repellency is observed in the high contact angles of water and oil on the surface of the coating and also in the sliding angle measurements: water and oil droplets leave no visible trace on the surface of the hybrid coatings and with DLC-PDMS-hybrid coating an extremely low sliding angle of only 0.15°±0.03° was measured with a 20 μl distilled water droplet (the lowest sliding angle value given in the literature is 1°)." @default.
- W2110348765 created "2016-06-24" @default.
- W2110348765 creator A5009290978 @default.
- W2110348765 date "2004-08-01" @default.
- W2110348765 modified "2023-09-28" @default.
- W2110348765 title "EXPERIMENTAL STUDIES ON DIAMOND-LIKE CARBON AND NOVEL DIAMOND-LIKE CARBON - POLYMER - HYBRID COATINGS" @default.
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