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- W2110361566 abstract "The pH dependence of thiolysis of 1,2-epoxides with thiophenol in water and the influence of a Lewis acid catalyst is investigated. InCl3 showed a very high efficiency in catalyzing this process at pH 4.0. The regioselectivity of the nucleophilic attack is markedly influenced going from pH 9.0 to pH 4.0. A one-pot procedure running solely in water to prepare trans-2-(phenylsulphinyl)cyclohexan-1-ol is reported starting from epoxycyclohexane, via thiolysis reaction and oxidation with t-butyl hydroperoxide." @default.
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- W2110361566 date "2010-05-19" @default.
- W2110361566 modified "2023-09-26" @default.
- W2110361566 title "ChemInform Abstract: Thiolysis of Alkyl- and Aryl-1,2-epoxides in Water Catalyzed by InCl3." @default.
- W2110361566 cites W2949208182 @default.
- W2110361566 doi "https://doi.org/10.1002/chin.200243052" @default.
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