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- W2110379827 abstract "The theory of optical activity is generalized to include the effects of molecular interactions arising from the moments induced by the electromagnetic field. It is shown that in the presence of these interactions the electric quadrupole terms do not vanish upon statistical averaging, thus giving rise to a new mechanism of solvent effect on optical activity. The theory is specialized to a dilute solution of optically active molecules in optically inactive solvents. It is predicted that for a 0.1 molar solution of optically active molecules having quadrupole polarizability of ≈10−40 (in SI units), the change in rotation is ≈6° m−1." @default.
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- W2110379827 date "1981-12-01" @default.
- W2110379827 modified "2023-09-28" @default.
- W2110379827 title "Solvent effect on optical activity in dilute solutions" @default.
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- W2110379827 doi "https://doi.org/10.1016/0301-0104(81)87012-7" @default.
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