FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2110385613> ?p ?o ?g. }

• W2110385613 endingPage "2385" @default.
• W2110385613 startingPage "2380" @default.
• W2110385613 abstract "Abstract The synthesis and characterization of two new cyano‐bridged cluster compounds, [Tp 2 (cyclen) 3 Ni II 3 Fe III 2 (CN) 6 ](BF 4 ) 4 ( 1 ) and [(Me 3 tacn) 5 Cu II 3 Cr III 2 (CN) 6 ](ClO 4 ) 6 ( 2 ), are reported. The structure of each cluster is based upon a trigonal bipyramidal geometry, and ferromagnetic coupling between constituent metal ions is shown to give rise to S = 4 and S = $rm ^{9}/_{2}$ ground states, respectively. A room‐temperature assembly reaction generates a purple form of compound 2 , wherein two cyanide stretching frequencies in the infrared spectrum ( ν CN = 2094, 2156 cm −1 ) indicate partial isomerism of the cyanide bridging ligands. The X‐ray crystal structure confirms this isomerism via examination of the C and N thermal parameters. At −40 °C, a metastable green form of the compound is instead isolated, for which a single cyanide stretch at ν CN = 2156 cm −1 is consistent with an unisomerized cluster. The temperature‐dependence of the magnetization under varying applied field reveals significant axial anisotropy in compound 1 , with a significant axial zero‐field splitting while compound 2 shows no zero‐field splitting in either isolated form. In line with the observed anisotropy, AC magnetic susceptibility measurements performed on compound 1 reveal a frequency‐dependent out‐of‐phase signal suggestive of single‐molecule magnet behavior." @default.
• W2110385613 created "2016-06-24" @default.
• W2110385613 creator A5031020528 @default.
• W2110385613 creator A5042591801 @default.
• W2110385613 creator A5058386936 @default.
• W2110385613 creator A5086170310 @default.
• W2110385613 date "2007-10-01" @default.
• W2110385613 modified "2023-10-11" @default.
• W2110385613 title "High-Spin Ni3Fe2(CN)6 and Cu3Cr2(CN)6 Clusters Based on a Trigonal Bipyramidal Geometry" @default.
• W2110385613 cites W1823409394 @default.
• W2110385613 cites W1964482411 @default.
• W2110385613 cites W1977863915 @default.
• W2110385613 cites W1978279738 @default.
• W2110385613 cites W1990654323 @default.
• W2110385613 cites W2003183176 @default.
• W2110385613 cites W2007163895 @default.
• W2110385613 cites W2013222875 @default.
• W2110385613 cites W2013279765 @default.
• W2110385613 cites W2018449516 @default.
• W2110385613 cites W2027870231 @default.
• W2110385613 cites W2050535345 @default.
• W2110385613 cites W2079580040 @default.
• W2110385613 cites W2080665513 @default.
• W2110385613 cites W2081214845 @default.
• W2110385613 cites W2081386044 @default.
• W2110385613 cites W2081715587 @default.
• W2110385613 cites W2082002130 @default.
• W2110385613 cites W2084576130 @default.
• W2110385613 cites W2084970647 @default.
• W2110385613 cites W2089740902 @default.
• W2110385613 cites W2094439305 @default.
• W2110385613 cites W2140099689 @default.
• W2110385613 cites W2161868393 @default.
• W2110385613 cites W2163657421 @default.
• W2110385613 cites W3136211107 @default.
• W2110385613 cites W4237560963 @default.
• W2110385613 cites W4247041245 @default.
• W2110385613 doi "https://doi.org/10.1002/zaac.200700273" @default.
• W2110385613 hasPublicationYear "2007" @default.
• W2110385613 type Work @default.
• W2110385613 sameAs 2110385613 @default.
• W2110385613 citedByCount "22" @default.
• W2110385613 countsByYear W21103856132012 @default.
• W2110385613 countsByYear W21103856132014 @default.
• W2110385613 countsByYear W21103856132015 @default.
• W2110385613 countsByYear W21103856132017 @default.
• W2110385613 countsByYear W21103856132021 @default.
• W2110385613 countsByYear W21103856132022 @default.
• W2110385613 crossrefType "journal-article" @default.
• W2110385613 hasAuthorship W2110385613A5031020528 @default.
• W2110385613 hasAuthorship W2110385613A5042591801 @default.
• W2110385613 hasAuthorship W2110385613A5058386936 @default.
• W2110385613 hasAuthorship W2110385613A5086170310 @default.
• W2110385613 hasConcept C111592845 @default.
• W2110385613 hasConcept C112887158 @default.
• W2110385613 hasConcept C115260700 @default.
• W2110385613 hasConcept C115624301 @default.
• W2110385613 hasConcept C121332964 @default.
• W2110385613 hasConcept C164866538 @default.
• W2110385613 hasConcept C178790620 @default.
• W2110385613 hasConcept C179104552 @default.
• W2110385613 hasConcept C185592680 @default.
• W2110385613 hasConcept C194196696 @default.
• W2110385613 hasConcept C199360897 @default.
• W2110385613 hasConcept C26873012 @default.
• W2110385613 hasConcept C2778455166 @default.
• W2110385613 hasConcept C32546565 @default.
• W2110385613 hasConcept C32909587 @default.
• W2110385613 hasConcept C32938098 @default.
• W2110385613 hasConcept C41008148 @default.
• W2110385613 hasConcept C62520636 @default.
• W2110385613 hasConcept C71240020 @default.
• W2110385613 hasConcept C8010536 @default.
• W2110385613 hasConcept C82217956 @default.
• W2110385613 hasConcept C85725439 @default.
• W2110385613 hasConceptScore W2110385613C111592845 @default.
• W2110385613 hasConceptScore W2110385613C112887158 @default.
• W2110385613 hasConceptScore W2110385613C115260700 @default.
• W2110385613 hasConceptScore W2110385613C115624301 @default.
• W2110385613 hasConceptScore W2110385613C121332964 @default.
• W2110385613 hasConceptScore W2110385613C164866538 @default.
• W2110385613 hasConceptScore W2110385613C178790620 @default.
• W2110385613 hasConceptScore W2110385613C179104552 @default.
• W2110385613 hasConceptScore W2110385613C185592680 @default.
• W2110385613 hasConceptScore W2110385613C194196696 @default.
• W2110385613 hasConceptScore W2110385613C199360897 @default.
• W2110385613 hasConceptScore W2110385613C26873012 @default.
• W2110385613 hasConceptScore W2110385613C2778455166 @default.
• W2110385613 hasConceptScore W2110385613C32546565 @default.
• W2110385613 hasConceptScore W2110385613C32909587 @default.
• W2110385613 hasConceptScore W2110385613C32938098 @default.
• W2110385613 hasConceptScore W2110385613C41008148 @default.
• W2110385613 hasConceptScore W2110385613C62520636 @default.
• W2110385613 hasConceptScore W2110385613C71240020 @default.
• W2110385613 hasConceptScore W2110385613C8010536 @default.
• W2110385613 hasConceptScore W2110385613C82217956 @default.
• W2110385613 hasConceptScore W2110385613C85725439 @default.
• W2110385613 hasIssue "13-14" @default.

• next