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- W2110408997 abstract "The versatile coordination behavior of the PNP ligands 1A (2,6-bis[(di-tert-butylphosphino)methyl]pyridine) and 1B (2,6-bis[(diphenylphosphino)methyl]pyridine) to CuI is described, whereby a hemilabile interaction of the pyridine N-donor atom to the copper center resulted in a rare T-shaped complex with 1A, while with 1B also a tetracoordinated species could be isolated. Theoretical calculations support the weak interaction of the pyridine N donor in 1A with the Cu center." @default.
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- W2110408997 date "2008-04-29" @default.
- W2110408997 modified "2023-10-07" @default.
- W2110408997 title "T-Shaped Cationic Cu<sup>I</sup> Complexes with Hemilabile PNP-Type Ligands" @default.
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- W2110408997 doi "https://doi.org/10.1021/ic800298a" @default.
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