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- W2110552707 abstract "Different sizes of core-functionalized metallodendritic wedges were prepared by anchoring sensor-active arylplatinum(II) sites at the focal point of Fréchet-type polyether dendritic wedges of various generations. The strong color of these metallodendrimers in the presence of SO2 was used to assess the permeability of nanofiltration membranes (molecular weight cut-off of 400 dalton) at ambient pressure. A primary result of these studies is that dendrimers do not have to be exceptionally large for successful retention. Hence, nanofiltration, membrane-capped. immersion vials were developed, which operate as sensor devices when loaded with metallodendrimers with good retention properties. Appropriate substitution of the dye site at the focal point of these metallodendritic wedges by a catalytically active group afforded dendritic catalysts that exhibit essentially the same physical properties (shape, retention) as the corresponding dyefunctionalized dendritic wedges. When this homogeneous catalyst is compartmentalized in membrane-capped vials, a unique and convenient method for its retrieval from product solutions is available. Moreover, such immobilized metallodendritic catalysts can be regenerated and stored for months without losing their activity; this provides access for the development of novel sustainable homogeneous catalysts." @default.
- W2110552707 created "2016-06-24" @default.
- W2110552707 creator A5024855793 @default.
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- W2110552707 creator A5067760028 @default.
- W2110552707 creator A5089521767 @default.
- W2110552707 date "2001-03-16" @default.
- W2110552707 modified "2023-10-16" @default.
- W2110552707 title "Multiple Use of Soluble Metallodendritic Materials as Catalysts and Dyes" @default.
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- W2110552707 doi "https://doi.org/10.1002/1521-3765(20010316)7:6<1289::aid-chem1289>3.0.co;2-6" @default.
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