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- W2110571824 abstract "Chemische Verschiebungen δ13C von Aminoboranen R2BNR′2 1 und X2BNR2′ 2 sowie von Borazinen (RBNR′)3 3 und (XBNR′)3 4 (X = F, Cl, Br, I, OR, SR, NR2) könen mit der Wirkung eines γ-Effektes von R und X auf δ13C(BC) und γ13C(NC) erklärt werden. Es bestehen Analogien zu Alkenen, Imoniumsalzen und Benzolderivaten. - Heteronucleare 13C{1H, 11B} Tripelresonanz-experimente erlauben die Betrachtung scharfer 13C(BC)-Resonanzsignale. NMR Spectroscopic Studies of Boron Compounds, XIX. 13C NMR Studies on Monoaminoboranes and Borazines Chemical shifts δ13C of aminoboranes R2BNR′2 1 and X2BNR′2 2 as well as of borazines (RBNR′)3 3 and (XBNR′)3 4 (X = F, Cl, Br, I, OR, SR, NR2) can be explained by the action of a γ-effect exerted by R and X on the shielding of 13 C(BC) and 13C(NC). Analogies exist with similar effects in alkenes, imonium slats and benzene derivatives. - Heteronuclear 13C{1H, 11B} triple resonance experiments permit the observation of sharp 13C(BC) resonance signals." @default.
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- W2110571824 date "1981-03-01" @default.
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- W2110571824 title "Kernresonanzspektroskopische Untersuchungen an Borverbindungen, XIX. <sup>13</sup> C‐NMR‐Studien an Monoaminoboranen und Borazinen" @default.
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- W2110571824 doi "https://doi.org/10.1002/cber.19811140332" @default.
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