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- W2110572085 abstract "Novel synthesis of cephalotaxine 1 based on tertiary N-acyliminium ion chemistry starting from alkynylamide 2 was achieved. The key steps include the preparation of pyrroloisoquinoline 4 from alkynylamide 2, the ring expansion of pyrroloisoquinoline 4 to pyrrolobenzazepine 12, and the construction of cyclopentapyrrolobenzazepine ring system 6, all of which are derived from N-acyliminium ion intermediates." @default.
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- W2110572085 date "2002-02-22" @default.
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- W2110572085 title "A Formal Total Synthesis of (±)-Cephalotaxine Using Sequential <i>N</i>-Acyliminium Ion Reactions" @default.
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- W2110572085 doi "https://doi.org/10.1021/ol017114f" @default.
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