Matches in SemOpenAlex for { <https://semopenalex.org/work/W2110631566> ?p ?o ?g. }
- W2110631566 endingPage "63474" @default.
- W2110631566 startingPage "63466" @default.
- W2110631566 abstract "The binap-based hydroxyphosphine-(η6-arene)–ruthenium(II) complexes [RuX{η6:κ1(P)-PPh2-binaphthyl}{PPh2(OH)}][OTf] (X = OTf (4), Cl (5)) have been evaluated as potential catalysts for the selective hydration of nitriles to primary amides. The triflate derivative 4 proved to be the most active, being able to hydrate a large variety of aromatic, heteroaromatic, α,β-unsaturated and aliphatic nitriles in pure water at 100 °C. The utility of complex 4 to promote the catalytic rearrangement of aldoximes has also been demonstrated. In addition, insights about the role played by the hydroxyphosphine ligand PPh2(OH) during the catalytic reactions are given." @default.
- W2110631566 created "2016-06-24" @default.
- W2110631566 creator A5013565916 @default.
- W2110631566 creator A5015000166 @default.
- W2110631566 creator A5025100690 @default.
- W2110631566 creator A5034044998 @default.
- W2110631566 creator A5080588686 @default.
- W2110631566 date "2014-11-18" @default.
- W2110631566 modified "2023-10-01" @default.
- W2110631566 title "Investigation of binap-based hydroxyphosphine arene–ruthenium(<scp>ii</scp>) complexes as catalysts for nitrile hydration" @default.
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