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- W2110659916 abstract "Pt2Cl2(μ-dppm)2, (dppm = Ph2PCH2PPh2) reacts with carbon disulphide to give Pt2Cl2(μ-CS2)(μ-dppm)2, the structure of which has been determined and shown to contain CS2 in an unusual C,S bridging mode. Despite coordination in this fashion, the chemistry of Pt2Cl2(μ-CS2)(μ-dppm)2 parallels that of a typical π-CS2 complex; thus with methyl iodide and methyltriflate the respective complexes [Pt2Cl2I(C[SMe]2)(μ-dppm)2]+ and [Pt2Cl2(μ-CS2Me)(μ-dppm)2]+ result." @default.
- W2110659916 created "2016-06-24" @default.
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- W2110659916 date "1981-05-01" @default.
- W2110659916 modified "2023-10-11" @default.
- W2110659916 title "The preparation, structure and reactivity of a bridging carbon disulphide complex of platinum, Pt2Cl2(μ-CS2)(μ-dppm)2" @default.
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- W2110659916 doi "https://doi.org/10.1016/s0022-328x(00)85540-0" @default.
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