FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2110694007> ?p ?o ?g. }

• W2110694007 endingPage "12848" @default.
• W2110694007 startingPage "12842" @default.
• W2110694007 abstract "Treatment of bis(phenylethynyl)silane (PhC⋮C)2SiR2 (R = Me (2a), Et (2b) or Ph (2c)) with Cp2ZrEt2 (1) (Cp = cyclopentadienyl) and H2O/CuCl in this order afforded (1E,3E)-1,4-diphenyl-1,3-butadiene (3) in 56−88% yields after hydrolysis. On the other hand, hydrolysis of the reaction mixture of 2a−h with Cp2ZrEt2 gave silacyclobutene derivatives 4a−h in 61−87% yields. Zirconium-containing intermediate 7 was obtained as crystals suitable for X-ray analysis when t-BuC5H4 was used as the ligands of a zirconocene derivative. Structure of 7 showed that the intermediate contained the zirconacyclobutene−silacyclobutene fused ring system. Reaction of silacyclobutene 4a with CuCl selectively opened the silacyclobutene ring. The further treatment of the reaction mixture with PhI in the presence of a catalytic amount of Pd(PPh3)4 gave 1,3,4-triphenyl-1-silyl-1,3-butadiene compound 16. Zirconacyclopentadienes with an alkynylsilyl group at the α-position afforded zirconacyclohexadiene derivatives 19 in 82−98% yields. When t-BuC5H4 was used as the ligands instead of two Cp, the structure was determined by X-ray analysis. The structure clearly showed that 19 had the zirconacyclohexadiene−silacyclobutene fused ring system." @default.
• W2110694007 created "2016-06-24" @default.
• W2110694007 creator A5000501841 @default.
• W2110694007 creator A5025918204 @default.
• W2110694007 creator A5033474482 @default.
• W2110694007 creator A5038314305 @default.
• W2110694007 creator A5042033606 @default.
• W2110694007 creator A5047382885 @default.
• W2110694007 creator A5063386411 @default.
• W2110694007 creator A5065148586 @default.
• W2110694007 date "1997-12-01" @default.
• W2110694007 modified "2023-10-10" @default.
• W2110694007 title "Zirconocene-Mediated Intramolecular Carbon−Carbon Bond Formation of Two Alkynyl Groups of Bis(alkynyl)silanes" @default.
• W2110694007 cites W1964455379 @default.
• W2110694007 cites W1978636719 @default.
• W2110694007 cites W1980834614 @default.
• W2110694007 cites W1983855469 @default.
• W2110694007 cites W1991477229 @default.
• W2110694007 cites W1997846736 @default.
• W2110694007 cites W1998598466 @default.
• W2110694007 cites W2004505101 @default.
• W2110694007 cites W2040455773 @default.
• W2110694007 cites W2041562983 @default.
• W2110694007 cites W2041917097 @default.
• W2110694007 cites W2044302801 @default.
• W2110694007 cites W2076449683 @default.
• W2110694007 cites W2106736121 @default.
• W2110694007 cites W2107158355 @default.
• W2110694007 cites W2147570582 @default.
• W2110694007 cites W2331242672 @default.
• W2110694007 cites W2949343769 @default.
• W2110694007 cites W2953134180 @default.
• W2110694007 cites W3026148335 @default.
• W2110694007 doi "https://doi.org/10.1021/ja972381v" @default.
• W2110694007 hasPublicationYear "1997" @default.
• W2110694007 type Work @default.
• W2110694007 sameAs 2110694007 @default.
• W2110694007 citedByCount "84" @default.
• W2110694007 countsByYear W21106940072012 @default.
• W2110694007 countsByYear W21106940072013 @default.
• W2110694007 countsByYear W21106940072014 @default.
• W2110694007 countsByYear W21106940072015 @default.
• W2110694007 countsByYear W21106940072017 @default.
• W2110694007 countsByYear W21106940072018 @default.
• W2110694007 countsByYear W21106940072020 @default.
• W2110694007 countsByYear W21106940072021 @default.
• W2110694007 countsByYear W21106940072022 @default.
• W2110694007 crossrefType "journal-article" @default.
• W2110694007 hasAuthorship W2110694007A5000501841 @default.
• W2110694007 hasAuthorship W2110694007A5025918204 @default.
• W2110694007 hasAuthorship W2110694007A5033474482 @default.
• W2110694007 hasAuthorship W2110694007A5038314305 @default.
• W2110694007 hasAuthorship W2110694007A5042033606 @default.
• W2110694007 hasAuthorship W2110694007A5047382885 @default.
• W2110694007 hasAuthorship W2110694007A5063386411 @default.
• W2110694007 hasAuthorship W2110694007A5065148586 @default.
• W2110694007 hasConcept C106159729 @default.
• W2110694007 hasConcept C111771559 @default.
• W2110694007 hasConcept C155647269 @default.
• W2110694007 hasConcept C161790260 @default.
• W2110694007 hasConcept C162324750 @default.
• W2110694007 hasConcept C178790620 @default.
• W2110694007 hasConcept C181458950 @default.
• W2110694007 hasConcept C185592680 @default.
• W2110694007 hasConcept C2778024649 @default.
• W2110694007 hasConcept C2778183973 @default.
• W2110694007 hasConcept C2780263894 @default.
• W2110694007 hasConcept C2780299520 @default.
• W2110694007 hasConcept C2780378348 @default.
• W2110694007 hasConcept C46062151 @default.
• W2110694007 hasConcept C5304478 @default.
• W2110694007 hasConcept C71240020 @default.
• W2110694007 hasConcept C75079739 @default.
• W2110694007 hasConcept C94412978 @default.
• W2110694007 hasConceptScore W2110694007C106159729 @default.
• W2110694007 hasConceptScore W2110694007C111771559 @default.
• W2110694007 hasConceptScore W2110694007C155647269 @default.
• W2110694007 hasConceptScore W2110694007C161790260 @default.
• W2110694007 hasConceptScore W2110694007C162324750 @default.
• W2110694007 hasConceptScore W2110694007C178790620 @default.
• W2110694007 hasConceptScore W2110694007C181458950 @default.
• W2110694007 hasConceptScore W2110694007C185592680 @default.
• W2110694007 hasConceptScore W2110694007C2778024649 @default.
• W2110694007 hasConceptScore W2110694007C2778183973 @default.
• W2110694007 hasConceptScore W2110694007C2780263894 @default.
• W2110694007 hasConceptScore W2110694007C2780299520 @default.
• W2110694007 hasConceptScore W2110694007C2780378348 @default.
• W2110694007 hasConceptScore W2110694007C46062151 @default.
• W2110694007 hasConceptScore W2110694007C5304478 @default.
• W2110694007 hasConceptScore W2110694007C71240020 @default.
• W2110694007 hasConceptScore W2110694007C75079739 @default.
• W2110694007 hasConceptScore W2110694007C94412978 @default.
• W2110694007 hasIssue "52" @default.
• W2110694007 hasLocation W21106940071 @default.
• W2110694007 hasOpenAccess W2110694007 @default.
• W2110694007 hasPrimaryLocation W21106940071 @default.
• W2110694007 hasRelatedWork W1985489999 @default.
• W2110694007 hasRelatedWork W1995483937 @default.

• next