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• W2110736484 abstract "Abstract X‐ray diffraction and differential scanning calorimeter (DSC) methods have been used to investigate the crystallization behavior and crystalline structure of hexamethylenediamine (HMDA)‐modified maleic‐anhydride‐grafted polypropylene/clay (PP‐ g ‐MA/clay) nanocomposites. These nanocomposites have been prepared by using HMDA to graft the PP‐ g ‐MA (designated as PP‐ g ‐HMA) and then mixing the PP‐ g ‐HMA polymer in hot xylene solution, with the organically modified montmorillonite. Both X‐ray diffraction data and transmission electron microscopy images of PP‐ g ‐HMA/clay nanocomposites indicate that most of the swellable silicate layers are exfoliated and randomly dispersed into PP‐ g ‐HMA matrix. DSC isothermal results revealed that introducing 5 wt % of clay into the PP‐ g ‐HMA structure causes strongly heterogeneous nucleation, which induced a change of the crystal growth process from a three‐dimensional crystal growth to a two‐dimensional spherulitic growth. Mechanical properties of PP‐ g ‐HMA/clay nanocomposites performed by dynamic mechanical analysis show significant improvements in the storage modulus when compared to neat PP‐ g ‐HMA. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 3242–3254, 2005" @default.
• W2110736484 created "2016-06-24" @default.
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• W2110736484 date "2005-10-03" @default.
• W2110736484 modified "2023-10-12" @default.
• W2110736484 title "Preparation and characterization of PP/clay nanocomposites based on modified polypropylene and clay" @default.
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• W2110736484 doi "https://doi.org/10.1002/polb.20605" @default.
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