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- W2110794093 abstract "The tellurenyl fluoride, 2-Me2NCH2C6H4TeF, was obtained from reaction of the tellurenyl iodide RTeI with AgF. The compound was unambiguously identified by 19F and 125Te NMR spectroscopy. The decomposition under disproportionation leads to the tellurium(IV) trifluoride, 2-Me2NCH2C6H4TeF3 and the ditelluride RTeTeR. The fluorination of the ditelluride, (2-Me2NCH2C6H4Te)2, with XeF2 results in pure RTeF3. The molecular structure of 2-Me2NCH2C6H4TeF3, the second structural characterized tellurium(IV) trifluoride, has been determined. Furthermore the syntheses of the new tellurium(IV) difluoride, (2-Me2NCH2C6H4)2TeF2, and corresponding tellurium(IV) diazide, (2-Me2NCH2C6H4)2Te(N3)2 as well as the tellurium(IV) triazide, 2-Me2NCH2C6H4Te(N3)3, and their characterization by spectroscopic methods were reported. During these investigations a rather interesting tellurium(VI) species was formed and the molecular structure of a subsequent product, [(2-Me2NHCH2C6H4)2TeF3O]2(SiF6), was elucidated. Theoretical investigations for the compounds containing the stabilizing 2-dimethylaminomethylphenyl substituent are illustrated." @default.
- W2110794093 created "2016-06-24" @default.
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- W2110794093 date "2007-08-01" @default.
- W2110794093 modified "2023-09-27" @default.
- W2110794093 title "Tellurium(IV) Fluorides and Azides containing the Nitrogen Donor Substituent R = 2-Me2NCH2C6H4; Crystal Structure of RTeF3 and of an Unusual Tellurium(VI) Fluoride Salt" @default.
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- W2110794093 doi "https://doi.org/10.1002/zaac.200700079" @default.
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