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- W2110979945 endingPage "16090" @default.
- W2110979945 startingPage "16083" @default.
- W2110979945 abstract "A new tetracarboxylate ligand having short and long arms formed 2D layer Zn(II) coordination polymer 1 with paddle-wheel secondary building units under solvothermal conditions. The framework undergoes solvent-specific single crystal-to-single crystal (SC-SC) transmetalation to produce 1Cu . With a sterically encumbered dipyridyl linker, the same ligand forms non-interpenetrated, 3D, pillared-layer Zn(II) metal-organic framework (MOF) 2, which takes part in SC-SC linker-exchange reactions to produce three daughter frameworks. The parent MOF 2 shows preferential incorporation of the longest linker in competitive linker-exchange experiments. All the 3D MOFs undergo complete SC-SC transmetalation with Cu(II) , whereby metal exchange in different solvents and monitoring of X-ray structures revealed that bulky solvated metal ions lead to ordering of the shortest linker in the framework, which confirms that the solvated metal ions enter through the pores along the linker axis." @default.
- W2110979945 created "2016-06-24" @default.
- W2110979945 creator A5019478816 @default.
- W2110979945 creator A5029384299 @default.
- W2110979945 creator A5054602608 @default.
- W2110979945 date "2015-09-18" @default.
- W2110979945 modified "2023-10-17" @default.
- W2110979945 title "Versatile Tailoring of Paddle‐Wheel Zn <sup>II</sup> Metal–Organic Frameworks through Single‐Crystal‐to‐Single‐Crystal Transformations" @default.
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- W2110979945 doi "https://doi.org/10.1002/chem.201502648" @default.
- W2110979945 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26383591" @default.
- W2110979945 hasPublicationYear "2015" @default.
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