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- W2111004058 abstract "Thermal expansion behavior of A2(MoO4)3 compounds, where A=Fe3+, Cr3+ and Al3+, was studied in static air in the temperature range of 298–1073 K by a thermo-dilatometer. All the compounds showed a positive thermal expansion in the beginning, followed by a phase transition and then a negative thermal expansion (NTE). They have a monoclinic unit cell at room temperature. The negative thermal expansion coefficients (NTEC) of Fe2(MoO4)3, Cr2(MoO4)3 and Al2(MoO4)3 are: −14.82×10−6 K−1, −9.39×10−6 K−1 and −2.83×10−6 K−1, respectively. It is for the first time that some of the transition metal molybdates are shown to exhibit NTE." @default.
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- W2111004058 date "2002-06-01" @default.
- W2111004058 modified "2023-10-02" @default.
- W2111004058 title "Phase transition and negative thermal expansion in A2(MoO4)3 system (A=Fe3+, Cr3+ and Al3+)" @default.
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- W2111004058 doi "https://doi.org/10.1016/s0925-8388(01)02003-5" @default.
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