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• W2111089268 abstract "A sequential allyl vinyl ether formation−Claisen rearrangement process catalyzed by a palladium(II)−phenanthroline complex is reported. The effects of allylic alcohol structure, type of vinylating agent, and palladium catalysts are discussed. This method provides a convenient approach to γ,δ-unsaturated aldehydes under mild conditions that avoid the use of toxic Hg(II) catalysts. The new methodology has been successfully demonstrated on the kilogram scale." @default.
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• W2111089268 date "2007-04-21" @default.
• W2111089268 modified "2023-10-15" @default.
• W2111089268 title "Tandem Pd(II)-Catalyzed Vinyl Ether Exchange−Claisen Rearrangement as a Facile Approach to γ,δ-Unsaturated Aldehydes" @default.
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• W2111089268 doi "https://doi.org/10.1021/jo062548f" @default.
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