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- W2111104011 endingPage "4143" @default.
- W2111104011 startingPage "4143" @default.
- W2111104011 abstract "Organic semiconductors containing metal binding sites within their molecular backbones are of a general interest in organic materials chemistry. In this paper, we describe a straightforward synthetic procedure, which gives access to a series of 2-(oligothienyl)-[1,10]phenanthrolines (nT-phen), 2,9-bis(oligothienyl)-[1,10]phenanthrolines (nT-phen-nT) and 2,2′-(oligothienyl)bis-[1,10]phenanthrolines (phen-nT-phen). By a Negishi-type cross coupling of 2-iodo-[1,10]phenanthroline or 2,9-diiodo-[1,10]phenanthroline with in situ generated α-zinc derivatives of different mono-, ter-, and quinquethiophenes we were able to synthesize the corresponding oligothienyl-phenanthrolines in medium to excellent yields. Furthermore, characterization of the optical properties of the new materials indicated that the two subunits, oligothiophene and phenanthroline, are in π-conjugation. Characterization of the redox properties revealed additional evidence for the role of [1,10]phenanthroline as a π-bridging unit in the nT-phen-nT series." @default.
- W2111104011 created "2016-06-24" @default.
- W2111104011 creator A5033083255 @default.
- W2111104011 creator A5060901286 @default.
- W2111104011 date "2005-01-01" @default.
- W2111104011 modified "2023-10-18" @default.
- W2111104011 title "Synthesis and electronic properties of series of oligothiophene-[1,10]phenanthrolines" @default.
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- W2111104011 doi "https://doi.org/10.1039/b508572a" @default.
- W2111104011 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16267596" @default.
- W2111104011 hasPublicationYear "2005" @default.
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