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- W2111268250 abstract "An intermolecular [2+2] cycloaddition reaction for the synthesis of 1,2-dimethylenecyclobutane derivatives from the commercially available starting materials aryl acetylenes, nBuLi, formamides, and trimethylsilyl cyanide (TMSCN) has been achieved. This reaction displays high regio- and stereoselectivities due to the captodative effect. The mechanism of the reaction has been investigated by the deuterium labeling experiments and DFT calculations." @default.
- W2111268250 created "2016-06-24" @default.
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- W2111268250 date "2015-08-21" @default.
- W2111268250 modified "2023-10-16" @default.
- W2111268250 title "Spontaneous Dimerization of Allenes in Situ: An Efficient Synthesis of Substituted 1,2-Dimethylenecyclobutanes with High Regio- and Stereoselectivities" @default.
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- W2111268250 doi "https://doi.org/10.1002/chem.201502503" @default.
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