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- W2111466365 abstract "Abstract Two groups of active centers in the system δ‐TiCl 3 /AlEt 3 have been found: the first one was formed by the interaction of TiCl 3 with AlEt 3 , and the other one was formed as the result of the reaction of TiCl 3 with AlEt 2 Cl which appeared after the alkylation reaction of TiCl 3 . There exists a distribution of active centers with respect of their activity and stereospecificity in both groups. By the influence of the donor an increase of the iso‐addition rate constant and the stereoregular ability of isotactic centers takes place." @default.
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- W2111466365 date "1983-11-01" @default.
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- W2111466365 title "Distribution of the centers with respect of activity and stereospecificity and their chemical nature in the catalytic system δ‐TiCl <sub>3</sub> /AlEt <sub>3</sub> and the possibility to affect them by addition of donors" @default.
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- W2111466365 doi "https://doi.org/10.1002/actp.1983.010341107" @default.
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