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• W2111495198 startingPage "n/a" @default.
• W2111495198 abstract "A wide range of 2,3-disubstituted quinoxalines have been successfully hydrogenated with H2 using borane catalysts to produce the desired tetrahydroquinoxalines in 80-99% yields with excellent cis selectivity. Significantly, the asymmetric reaction employing chiral borane catalysts generated by the in situ hydroboration of chiral dienes with HB(C6F5)2 under mild reaction conditions has also been achieved with up to 96% ee, and represents the first catalytic asymmetric system to furnish optically active cis-2,3-disubstituted 1,2,3,4-tetrahydroquinoxalines." @default.
• W2111495198 created "2016-06-24" @default.
• W2111495198 creator A5023431404 @default.
• W2111495198 creator A5038002804 @default.
• W2111495198 date "2014-11-13" @default.
• W2111495198 modified "2023-10-11" @default.
• W2111495198 title "A Highly<i>cis</i>-Selective and Enantioselective Metal-Free Hydrogenation of 2,3-Disubstituted Quinoxalines" @default.
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• W2111495198 doi "https://doi.org/10.1002/anie.201409471" @default.
• W2111495198 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25393413" @default.
• W2111495198 hasPublicationYear "2014" @default.
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