Matches in SemOpenAlex for { <https://semopenalex.org/work/W2111525462> ?p ?o ?g. }
- W2111525462 endingPage "2210" @default.
- W2111525462 startingPage "2199" @default.
- W2111525462 abstract "Abstract Time‐series hydrothermal syntheses from two organic‐cation‐free gels with different compositions were employed to study the factors that control the final size of zeolite L crystals. The first gel had a starting K/Al ratio of 10, whereas in the second one it was three times lower. The relatively simple chemical composition of the starting gels and the combination of complementary characterization methods allowed us to track down the different stages of transformation of the initial amorphous gels into zeolite crystals and the factors that control the nucleation and growth processes. The role of the starting mixture components in the formation of the primary amorphous particles was explored. It was found that the profoundly different reaction kinetics in the two systems are caused by the difference in diffusion rates, which in turn are controlled by the extent of the polymerization reactions at room temperature during mixing of the starting components prior to hydrothermal treatment. As a consequence, nucleation is fast and ubiquitous in the first system with higher water content and K/Al ratio, whereas it is slow and sporadic in the second system with lower water content and K/Al ratio. Ultimately, these differences in the kinetics lead to the formation of two distinctly different patterns of crystal‐size distribution, with a large number of small nanocrystals in the first sample and fewer large crystals in the second sample. The new findings put zeolite crystal growth on a rational basis that would enable the control of zeolite crystal size in similar organic‐template‐free systems." @default.
- W2111525462 created "2016-06-24" @default.
- W2111525462 creator A5007446622 @default.
- W2111525462 creator A5015870445 @default.
- W2111525462 creator A5023686070 @default.
- W2111525462 creator A5033407896 @default.
- W2111525462 creator A5086086513 @default.
- W2111525462 date "2011-01-10" @default.
- W2111525462 modified "2023-10-18" @default.
- W2111525462 title "Factors That Control Zeolite L Crystal Size" @default.
- W2111525462 cites W105942964 @default.
- W2111525462 cites W14356219 @default.
- W2111525462 cites W1565609502 @default.
- W2111525462 cites W1652940835 @default.
- W2111525462 cites W1968225768 @default.
- W2111525462 cites W1969555886 @default.
- W2111525462 cites W1972401820 @default.
- W2111525462 cites W1974220845 @default.
- W2111525462 cites W1975299796 @default.
- W2111525462 cites W1977522600 @default.
- W2111525462 cites W1979255569 @default.
- W2111525462 cites W1980716863 @default.
- W2111525462 cites W1981182226 @default.
- W2111525462 cites W1986742995 @default.
- W2111525462 cites W1987138171 @default.
- W2111525462 cites W1988430172 @default.
- W2111525462 cites W1989557485 @default.
- W2111525462 cites W1992231693 @default.
- W2111525462 cites W1993878779 @default.
- W2111525462 cites W1995033896 @default.
- W2111525462 cites W1996034367 @default.
- W2111525462 cites W1998895116 @default.
- W2111525462 cites W1999092592 @default.
- W2111525462 cites W2002751060 @default.
- W2111525462 cites W2006343833 @default.
- W2111525462 cites W2007654012 @default.
- W2111525462 cites W2010519199 @default.
- W2111525462 cites W2011784182 @default.
- W2111525462 cites W2012948478 @default.
- W2111525462 cites W2022646981 @default.
- W2111525462 cites W2026355881 @default.
- W2111525462 cites W2026774108 @default.
- W2111525462 cites W2028504694 @default.
- W2111525462 cites W2031731692 @default.
- W2111525462 cites W2035176265 @default.
- W2111525462 cites W2036698206 @default.
- W2111525462 cites W2038144447 @default.
- W2111525462 cites W2041124586 @default.
- W2111525462 cites W2048401523 @default.
- W2111525462 cites W2051152845 @default.
- W2111525462 cites W2055121733 @default.
- W2111525462 cites W2056228325 @default.
- W2111525462 cites W2058899696 @default.
- W2111525462 cites W2059180359 @default.
- W2111525462 cites W2063650469 @default.
- W2111525462 cites W2063766434 @default.
- W2111525462 cites W2069677750 @default.
- W2111525462 cites W2072706753 @default.
- W2111525462 cites W2077963920 @default.
- W2111525462 cites W2078427679 @default.
- W2111525462 cites W2081324883 @default.
- W2111525462 cites W2089069588 @default.
- W2111525462 cites W2089612576 @default.
- W2111525462 cites W2089731998 @default.
- W2111525462 cites W2090526116 @default.
- W2111525462 cites W2091480993 @default.
- W2111525462 cites W2095533084 @default.
- W2111525462 cites W2097487143 @default.
- W2111525462 cites W2107226996 @default.
- W2111525462 cites W2115804212 @default.
- W2111525462 cites W2119216672 @default.
- W2111525462 cites W2124691604 @default.
- W2111525462 cites W2128180677 @default.
- W2111525462 cites W2133522226 @default.
- W2111525462 cites W2135751038 @default.
- W2111525462 cites W2153307087 @default.
- W2111525462 cites W2204040874 @default.
- W2111525462 cites W3022208951 @default.
- W2111525462 cites W4235536385 @default.
- W2111525462 cites W4240835118 @default.
- W2111525462 cites W4255132424 @default.
- W2111525462 doi "https://doi.org/10.1002/chem.201002622" @default.
- W2111525462 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21294184" @default.
- W2111525462 hasPublicationYear "2011" @default.
- W2111525462 type Work @default.
- W2111525462 sameAs 2111525462 @default.
- W2111525462 citedByCount "35" @default.
- W2111525462 countsByYear W21115254622012 @default.
- W2111525462 countsByYear W21115254622013 @default.
- W2111525462 countsByYear W21115254622014 @default.
- W2111525462 countsByYear W21115254622015 @default.
- W2111525462 countsByYear W21115254622016 @default.
- W2111525462 countsByYear W21115254622017 @default.
- W2111525462 countsByYear W21115254622018 @default.
- W2111525462 countsByYear W21115254622019 @default.
- W2111525462 countsByYear W21115254622020 @default.
- W2111525462 countsByYear W21115254622021 @default.
- W2111525462 countsByYear W21115254622022 @default.